Cleavage of carbon-carbon bonds. Copper(II)-induced oxygenolysis of o-benzoquinones, catechols, and phenols. On the question of nonenzymic oxidation of aromatics and activation of molecular oxygen

Milorad M. Rogic; Timothy R. Demmin

doi:10.1021/ja00485a035

Cleavage of carbon-carbon bonds. Copper(II)-induced oxygenolysis of o-benzoquinones, catechols, and phenols. On the question of nonenzymic oxidation of aromatics and activation of molecular oxygen

Journal of the American Chemical Society ◽

10.1021/ja00485a035 ◽

1978 ◽

Vol 100 (17) ◽

pp. 5472-5487 ◽

Cited By ~ 97

Author(s):

Milorad M. Rogic ◽

Timothy R. Demmin

Keyword(s):

Molecular Oxygen ◽

Carbon Carbon Bonds ◽

Carbon Bonds

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ChemInform Abstract: Gold-Catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers Using Molecular Oxygen. Simultaneous Degradation of C-H and Single and Triple Carbon-Carbon Bonds under Ambient Conditions.

ChemInform ◽

10.1002/chin.200946080 ◽

2009 ◽

Vol 40 (46) ◽

Author(s):

Arindam Das ◽

Rupsha Chaudhuri ◽

Rai-Shung Liu

Keyword(s):

Molecular Oxygen ◽

Oxidative Cleavage ◽

Ambient Conditions ◽

Carbon Carbon Bonds ◽

Carbon Bonds ◽

Simultaneous Degradation

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ChemInform Abstract: CLEAVAGE OF CARBON-CARBON BONDS. COPPER(II)-INDUCED OXYGENOLYSIS OF O-BENZOQUINONES, CATECHOLS, AND PHENOLS. ON THE QUESTION OF NONENZYMIC OXIDATION OF AROMATICS AND ACTIVATION OF MOLECULAR OXYGEN

Chemischer Informationsdienst ◽

10.1002/chin.197849119 ◽

1978 ◽

Vol 9 (49) ◽

Author(s):

M. M. ROGIC ◽

T. R. DEMMIN

Keyword(s):

Molecular Oxygen ◽

Carbon Carbon Bonds ◽

Carbon Bonds

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Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C–H and single and triple carbon–carbon bonds under ambient conditions

Chemical Communications ◽

10.1039/b908338c ◽

2009 ◽

pp. 4046 ◽

Cited By ~ 33

Author(s):

Arindam Das ◽

Rupsha Chaudhuri ◽

Rai-Shung Liu

Keyword(s):

Molecular Oxygen ◽

Oxidative Cleavage ◽

Ambient Conditions ◽

Carbon Carbon Bonds ◽

Carbon Bonds ◽

Simultaneous Degradation

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ChemInform Abstract: REACTIONS OF THE IRON AND COBALT CARBENES FECH2+ AND COCH2+ WITH ALIPHATIC ALKANES IN THE GAS PHASE. ACTIVATION OF CARBON-HYDROGEN AND CARBON-CARBON BONDS BY NAKED TRANSITION-METAL CARBENE IONS

Chemischer Informationsdienst ◽

10.1002/chin.198545266 ◽

1985 ◽

Vol 16 (45) ◽

Author(s):

D. B. JACOBSON ◽

B. S. FREISER

Keyword(s):

Transition Metal ◽

Gas Phase ◽

Carbon Carbon Bonds ◽

Carbon Bonds

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ChemInform Abstract: DIRECTED CLEAVAGE OF CARBON-CARBON BONDS BY TRANSITION METALS: THE α-BONDS OF KETONES

Chemischer Informationsdienst ◽

10.1002/chin.198433275 ◽

1984 ◽

Vol 15 (33) ◽

Author(s):

J. W. SUGGS ◽

C.-H. JUN

Keyword(s):

Transition Metals ◽

Carbon Carbon Bonds ◽

Carbon Bonds

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Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon–carbon bonds

Organic & Biomolecular Chemistry ◽

10.1039/c7ob00235a ◽

2017 ◽

Vol 15 (10) ◽

pp. 2163-2167 ◽

Cited By ~ 14

Author(s):

Zhouting Rong ◽

Antonio M. Echavarren

Keyword(s):

Single Step ◽

Simultaneous Formation ◽

Broad Scope ◽

Carbon Carbon Bonds ◽

Carbon Bonds ◽

First Time ◽

High Stereoselectivity

The polycyclisation of polyeneynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon–carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings.

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