Computational Study on Mechanisms and Origins of Selectivities in Rh(I)-Catalyzed Cycloisomerizations of 1,6-Allenynes with Tethered Unsaturated Carbon–Carbon Bonds

ACS Catalysis ◽  
2021 ◽  
pp. 4770-4783
Author(s):  
Qianqian Lu ◽  
Jun Gu ◽  
Fang Liu ◽  
Chunsen Li
2017 ◽  
Vol 15 (10) ◽  
pp. 2163-2167 ◽  
Author(s):  
Zhouting Rong ◽  
Antonio M. Echavarren

The polycyclisation of polyeneynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon–carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings.


ChemInform ◽  
2010 ◽  
Vol 28 (4) ◽  
pp. no-no
Author(s):  
S. F. SELLERS

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