The relationship of thermodynamic data for base adduct formation with cobalt protoporphyrin IX dimethyl ester to the corresponding enthalpies of forming dioxygen adducts with implications to oxygen binding cooperativity

1978 ◽  
Vol 100 (17) ◽  
pp. 5374-5382 ◽  
Author(s):  
Russell S. Drago ◽  
Tony Beugelsdijk ◽  
John A. Breese ◽  
J. Patrick Cannady
2019 ◽  
Vol 11 (12) ◽  
Author(s):  
Agata Szade ◽  
Krzysztof Szade ◽  
Witold N Nowak ◽  
Karolina Bukowska‐Strakova ◽  
Lucie Muchova ◽  
...  

1985 ◽  
Vol 40 (7-8) ◽  
pp. 490-495 ◽  
Author(s):  
Edith Lohaus ◽  
Claudia Zenger ◽  
Wolfhart Rüdiger ◽  
Edmund Cmiel

Abstract The new α-pyrone derivative II was isolated in crystalline form from extracts of dormant seeds of Rosa canina. It inhibits germination of seeds of Amaranthus caudatus completely, but reversibly, at conc. > 2.5 × 10-5 м . Its chemical structure was elucidated by mass spectrometry, 1H-and 13C-NMR spectroscopy to be 3-methyl-1-oxa-bicyclo (4,1,0) hept-5-en-2-one-4,6-dicarboxylic acid di­methylester (II). It is derived from 3-methyl-2H-pyran-2-one-4,6-dicarboxylic acid by cyclo-propanation with diazomethane. The parent compound which is a natural product of the seeds of Rosa canina was isolated as its dimethyl ester I the structure of which was elucidated by mass and NMR spectroscopy. I shows less inhibition of seed germination than II. The reference a-pyrones dimethyl-6-methyl-2H-pyran-2-one-3,5-dicarboxylate (III) , 3-methoxycarbonyl-5-methoxycar-bonylmethyl-6-methyl-2H-pyran-2-one (IV), and isodehydracetic acid methylester (V) did not show any inhibitory activity. The relationship of II with threo-dihydrohematinic acid (VII) is discussed.


2016 ◽  
Vol 120 (3) ◽  
pp. 790-804 ◽  
Author(s):  
I. Assunção-Miranda ◽  
C. Cruz-Oliveira ◽  
R.L.S. Neris ◽  
C.M. Figueiredo ◽  
L.P.S. Pereira ◽  
...  

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