Mechanism of formation of Grignard reagents

1978 ◽  
Vol 100 (10) ◽  
pp. 3163-3166 ◽  
Author(s):  
E. A. Vogler ◽  
R. L. Stein ◽  
J. M. Hayes
Keyword(s):  
Grignard Reagents ◽  
Mechanism Of Formation

Mechanism of formation of Grignard reagents. Kinetics of reaction of alkyl halides in diethyl ether with magnesium

1980 ◽  
Vol 102 (1) ◽  
pp. 217-226 ◽  
Author(s):  
Harold R. Rogers ◽  
Craig L. Hill ◽  
Yuzo Fujiwara ◽  
Randall J. Rogers ◽  
H. Lee Mitchell ◽  
...  
Keyword(s):  
Diethyl Ether ◽  
Alkyl Halides ◽  
Grignard Reagents ◽  
Mechanism Of Formation ◽  
Kinetics Of Reaction ◽  
Kinetics Of

Mechanism of formation of Grignard reagents. Corrosion of metallic magnesium by alkyl halides in ethers

1980 ◽  
Vol 45 (6) ◽  
pp. 1020-1028 ◽  
Author(s):  
Craig L. Hill ◽  
John B. Vander Sande ◽  
George M. Whitesides
Keyword(s):  
Alkyl Halides ◽  
Grignard Reagents ◽  
Mechanism Of Formation ◽  
Metallic Magnesium

Preparation of 1-Adamantyl Ketones: Structure, Mechanism of Formation and Biological Activity of Potential By-Products

2006 ◽  
Vol 71 (5) ◽  
pp. 709-722 ◽  
Author(s):  
Robert Vícha ◽  
Marek Nečas ◽  
Milan Potáček
Keyword(s):  
Biological Activity ◽  
Grignard Reagents ◽  
Adamantane Derivatives ◽  
Mechanism Of Formation ◽  
Carbonyl Chloride ◽  
Leaving Group ◽  
Ar Process ◽  
By Products

Reactions between adamantane-1-carbonyl chloride and several Grignard reagents as well as interactions with solvents have been examined. Some new and unexpected adamantane derivatives were isolated, fully characterized and their biological activity determined. In particular, an unexpected isochromanone 16 was formed in an SEAr process, in which a stable hydrocarbon was the leaving group.

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