Kinetic ambiguity between the Id and D mechanisms in ligand substitution reactions. The intimate mechanism for axial base-ligand exchange reactions in alkyl(base)cobaloximes and related species

J. A. Ewen; D. J. Darensbourg

doi:10.1021/ja00430a055

Kinetic ambiguity between the Id and D mechanisms in ligand substitution reactions. The intimate mechanism for axial base-ligand exchange reactions in alkyl(base)cobaloximes and related species

Journal of the American Chemical Society ◽

10.1021/ja00430a055 ◽

1976 ◽

Vol 98 (14) ◽

pp. 4317-4319 ◽

Cited By ~ 13

Author(s):

J. A. Ewen ◽

D. J. Darensbourg

Keyword(s):

Related Species ◽

Ligand Exchange ◽

Ligand Substitution ◽

Exchange Reactions ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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ChemInform Abstract: KINETIC AMBIGUITY BETWEEN THE ID AND D MECHANISMS IN LIGAND SUBSTITUTION REACTIONS. THE INTIMATE MECHANISM FOR AXIAL BASE-LIGAND EXCHANGE REACTIONS IN ALKYL(BASE)COBALOXIMES AND RELATED SPECIES

Chemischer Informationsdienst ◽

10.1002/chin.197640167 ◽

1976 ◽

Vol 7 (40) ◽

pp. no-no

Author(s):

J. A. EWEN ◽

D. J. DARENSBOURG

Keyword(s):

Related Species ◽

Ligand Exchange ◽

Ligand Substitution ◽

Exchange Reactions ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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Physical properties, ligand substitution reactions, and biological activity of Co(iii)-Schiff base complexes

Dalton Transactions ◽

10.1039/c8dt04606a ◽

2019 ◽

Vol 48 (18) ◽

pp. 5987-6002 ◽

Cited By ~ 5

Author(s):

A. Paden King ◽

Hendryck A. Gellineau ◽

Samantha N. MacMillan ◽

Justin J. Wilson

Keyword(s):

Biological Activity ◽

Schiff Base ◽

Physical Properties ◽

Ligand Exchange ◽

Ligand Substitution ◽

Schiff Base Complexes ◽

Substitution Reactions ◽

Anticancer Properties ◽

Ligand Substitution Reactions

A subset of fluorinated Co(iii) Schiff base complexes was synthesized, and their structural, ligand exchange, and anticancer properties were investigated.

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1700657: Impact of chloride concentration on ligand substitution reactions of zinc(II) complexes with biologically relevant nitrogen nucleophiles-ESI

Progress in Reaction Kinetics and Mechanism ◽

10.3184/146867818x15319903829245 ◽

2018 ◽

Keyword(s):

Chloride Concentration ◽

Ligand Substitution ◽

Substitution Reactions ◽

Biologically Relevant ◽

Nitrogen Nucleophiles ◽

Ligand Substitution Reactions

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Dinuclear nitrido-bridged ruthenium complexes bearing diimine ligands

Dalton Transactions ◽

10.1039/c7dt03085a ◽

2017 ◽

Vol 46 (41) ◽

pp. 14256-14263 ◽

Cited By ~ 3

Author(s):

Julie Urgiles ◽

Sarah R. Nathan ◽

Samantha N. MacMillan ◽

Justin J. Wilson

Keyword(s):

Calcium Uptake ◽

Ruthenium Complexes ◽

Ligand Substitution ◽

Mitochondrial Calcium ◽

Substitution Reactions ◽

Uptake Inhibition ◽

Diimine Ligands ◽

Mitochondrial Calcium Uptake ◽

Ligand Substitution Reactions

Nitrido-bridged ruthenium complexes are synthesized via ligand substitution reactions and evaluated for mitochondrial calcium uptake inhibition.

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Synthetic analogs of the active sites of iron-sulfur proteins. X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2-

Journal of the American Chemical Society ◽

10.1021/ja00836a011 ◽

1975 ◽

Vol 97 (3) ◽

pp. 528-533 ◽

Cited By ~ 37

Author(s):

Gary R. Dukes ◽

R. H. Holm

Keyword(s):

Active Sites ◽

Ligand Substitution ◽

Kinetics And Mechanism ◽

Substitution Reactions ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters ◽

Ligand Substitution Reactions

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Kinetic and spectrophotometric determination of trace zinc(II) in the presence of a large amount of lead(II) using ligand-substitution reactions of their metalloporphyrins with EDTA.

Analytical Sciences ◽

10.2116/analsci.5.719 ◽

1989 ◽

Vol 5 (6) ◽

pp. 719-724 ◽

Cited By ~ 8

Author(s):

Masaaki TABATA ◽

Naoko KAJIHARA

Keyword(s):

Spectrophotometric Determination ◽

Ligand Substitution ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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Axial ligand substitution reactions of iron(II) phthalocyanine adducts

Inorganic Chemistry ◽

10.1021/ic50209a065 ◽

1980 ◽

Vol 19 (7) ◽

pp. 2162-2165 ◽

Cited By ~ 23

Author(s):

Jens Martinsen ◽

Michael Miller ◽

Daria Trojan ◽

D. A. Sweigart

Keyword(s):

Ligand Substitution ◽

Axial Ligand ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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ChemInform Abstract: Associative Ligand Substitution Reactions of Low-Valent Rhenium-Oxo Compounds. Crystal and Molecular Structures of (ReO(MeCCMe)2L)SbF6, L = Pyridine and 4,4′-Dimethyl-2,2′-bipyridine.

ChemInform ◽

10.1002/chin.198721238 ◽

1987 ◽

Vol 18 (21) ◽

Author(s):

J. M. MAYER ◽

T. H. TULIP ◽

J. C. CALABRESE ◽

E. VALENCIA

Keyword(s):

Ligand Substitution ◽

Molecular Structures ◽

Substitution Reactions ◽

Crystal And Molecular Structures ◽

Low Valent ◽

Oxo Compounds ◽

Ligand Substitution Reactions

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ChemInform Abstract: AXIAL LIGAND SUBSTITUTION REACTIONS OF RUTHENIUM(II) PHTHALOCYANINE

Chemischer Informationsdienst ◽

10.1002/chin.198137301 ◽

1981 ◽

Vol 12 (37) ◽

Author(s):

M. M. DOEFF ◽

D. A. SWEIGART

Keyword(s):

Ligand Substitution ◽

Axial Ligand ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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COORDINATION SELECTIVITY AND LIGAND SUBSTITUTION REACTIONS OF AN ALUMINUM(III) COMPLEX WITH 8-HYDROXY-7-[(2 ' -CARBOXY-1 ' -PHENYL)-AZO]QUINOLINE-5-SULFONIC ACID

Journal of Coordination Chemistry ◽

10.1080/00958978408073871 ◽

1984 ◽

Vol 13 (3) ◽

pp. 221-230 ◽

Cited By ~ 10

Author(s):

Ikuko Ohkura ◽

Kiyoshi Fujiwara ◽

Ken-Ichi Okamoto ◽

Jinsai Hidaka ◽

Hisahiko Einaga

Keyword(s):

Sulfonic Acid ◽

Ligand Substitution ◽

Substitution Reactions ◽

Ligand Substitution Reactions

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