Axial ligand substitution reactions of iron(II) phthalocyanine adducts

1980 ◽  
Vol 19 (7) ◽  
pp. 2162-2165 ◽  
Author(s):  
Jens Martinsen ◽  
Michael Miller ◽  
Daria Trojan ◽  
D. A. Sweigart
Keyword(s):  
Ligand Substitution ◽  
Axial Ligand ◽  
Substitution Reactions ◽  
Ligand Substitution Reactions

scholarly journals Synthesis, Characterisation and Anti-Fungal Activities of Some New Copper(II) Complexes of Octamethyl Tetraaza-Cyclotetradecadiene

1999 ◽  
Vol 6 (6) ◽  
pp. 345-354 ◽  
Author(s):  
Tapashi G. Roy ◽  
Saroj K. S. Hazari ◽  
Benu K. Dey ◽  
Samar Chakraborti ◽  
Edward R. T. Tiekink
Keyword(s):  
Ligand Substitution ◽  
Phytopathogenic Fungi ◽  
Axial Ligand ◽  
Free State ◽  
Substitution Reactions ◽  
Conductance Data ◽  
Anti Fungal ◽  
Ligand Substitution Reactions

The ligand Me8[14]diene, L, in its free state as well as in the dihydroperchlorate form, L.2HClO4, coordinates copper(ll) in different salts to yield a series of [CuLXx]Xy(H2O)z complexes where X = NO3, ClO4, NCS, Cl and Br; x and y may have values of 0 or 2 and z = 0, 1 or 2. The complex, [CuL(ClO4)2].2H2O is found to undergo axial ligand substitution reactions with SCN- , NO3- and Cl- to give a variety of substitution derivatives: [CuL(ClO4)mXn] where X = NCS, NO3 and Cl; m = 0 or 1, and n = 1 or 2. The complexes .have been characterised on the basis of analytical, spectroscopic, magnetic and conductance data. The anti-fungal activities of the ligand and its complexes have been investigated against a range of phytopathogenic fungi.

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