Synthesis, molecular structure, and exchange coupling in the alternatingly bridged and alternatingly spaced linear-chain compound catena-dichloro(3,6-dithiaoctane)copper(II)

1982 ◽  
Vol 104 (24) ◽  
pp. 6627-6631 ◽  
Author(s):  
Marilyn M. Olmstead ◽  
W. Kenneth Musker ◽  
Leonard W. Ter Haar ◽  
William E. Hatfield
Keyword(s):  
Molecular Structure ◽  
Exchange Coupling ◽  
Linear Chain ◽  
Chain Compound

Crystal and Molecular Structure of a New Linear Chain Compound: Bis(diphenylglyoximato)platinum(III)perchlorate

1978 ◽  
Vol 33 (8) ◽  
pp. 843-848 ◽  
Author(s):  
H. Endres ◽  
H. J. Keller ◽  
H. van de Sand ◽  
Vu Dong
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Linear Chain ◽  
Formula Unit ◽  
Humid Atmosphere ◽  
Space Group ◽  
Group D ◽  
Chain Compound

Abstract The reaction of bis(diphenylglyoximato)platinum(IV) diiodide with AgClO4 in benzene yields red brown needles of the compound bis(diphenylglyoximato)platinum(III) perchlorate (A) and crystals of bis(diphenylglyoximato)platinum(III) perchlorate which contains additionally between one and one and a half moles of benzene per formula unit (B). Both compounds are highly hygroscopic and instantaneously change their color to black-green in a humid atmosphere. Crystals of A are tetragonal, a = 20.325(2), c - 6.519(4) Å, space group D84h-P4/ncc, Z = 4. The structure consists of stacks of [Pt(dpg)2]+ cations with equidistant Pt-Pt separations of 3.259(4) Å. The Perchlorate ions are disordered in channels formed by the cation columns. Crystals of B are triclinic, a = 14.29(3), b = 13.54(2), c -10.34(3) Å, a = 85.2(2), β = 113.2(2), γ = 93.9(2)°.

Molecular structure and magnetic properties of a linear chain compound, Ru2(O2CCMePh2)4Cl

Polyhedron ◽  
1993 ◽  
Vol 12 (6) ◽  
pp. 607-611 ◽  
Author(s):  
F.Albert Cotton ◽  
Youngmee Kim ◽  
Tong Ren
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Linear Chain ◽  
Chain Compound

One-dimensional magnetism of a linear chain compound containing yttrium(III) and a nitronyl nitroxide radical

1989 ◽  
Vol 28 (16) ◽  
pp. 3230-3234 ◽  
Author(s):  
Cristiano Benelli ◽  
Andrea Caneschi ◽  
Dante Gatteschi ◽  
Luca Pardi ◽  
Paul Rey
Keyword(s):  
Linear Chain ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
One Dimensional ◽  
Chain Compound

POSSIBLE CORRELATION OF THE ANOMALOUS THERMAL BEHAVIOR OF NbSe3 TO MOBILE DEFECTS

1991 ◽  
Vol 05 (14n15) ◽  
pp. 1013-1017
Author(s):  
IOAN BÂLDEA
Keyword(s):  
Thermal Behavior ◽  
Thermal Hysteresis ◽  
Linear Chain ◽  
Defect Distribution ◽  
Impurity Defect ◽  
Latent Heats ◽  
Chain Compound

The model of quasi-regular impurity (defect) distribution driven by CDW is used to suggest a possible explanation of the anomalous thermal behavior (thermal hysteresis, latent heats, etc.) found at the CDW transitions in the linear chain compound NbSe 3.

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