Preparation and structure of a new kind of an extended partially oxidized linear-chain compound: catena-(.mu.-bromo)bis((1R,2R)-cyclohexanediamine)nickel(2.77) bromide

1984 ◽  
Vol 23 (25) ◽  
pp. 4261-4265 ◽  
Author(s):  
Hans Toftlund ◽  
Ole Simonsen
Keyword(s):  
1989 ◽  
Vol 28 (16) ◽  
pp. 3230-3234 ◽  
Author(s):  
Cristiano Benelli ◽  
Andrea Caneschi ◽  
Dante Gatteschi ◽  
Luca Pardi ◽  
Paul Rey

1991 ◽  
Vol 05 (14n15) ◽  
pp. 1013-1017
Author(s):  
IOAN BÂLDEA

The model of quasi-regular impurity (defect) distribution driven by CDW is used to suggest a possible explanation of the anomalous thermal behavior (thermal hysteresis, latent heats, etc.) found at the CDW transitions in the linear chain compound NbSe 3.


1978 ◽  
Vol 33 (8) ◽  
pp. 843-848 ◽  
Author(s):  
H. Endres ◽  
H. J. Keller ◽  
H. van de Sand ◽  
Vu Dong

Abstract The reaction of bis(diphenylglyoximato)platinum(IV) diiodide with AgClO4 in benzene yields red brown needles of the compound bis(diphenylglyoximato)platinum(III) perchlorate (A) and crystals of bis(diphenylglyoximato)platinum(III) perchlorate which contains additionally between one and one and a half moles of benzene per formula unit (B). Both compounds are highly hygroscopic and instantaneously change their color to black-green in a humid atmosphere. Crystals of A are tetragonal, a = 20.325(2), c - 6.519(4) Å, space group D84h-P4/ncc, Z = 4. The structure consists of stacks of [Pt(dpg)2]+ cations with equidistant Pt-Pt separations of 3.259(4) Å. The Perchlorate ions are disordered in channels formed by the cation columns. Crystals of B are triclinic, a = 14.29(3), b = 13.54(2), c -10.34(3) Å, a = 85.2(2), β = 113.2(2), γ = 93.9(2)°.


2016 ◽  
Vol 45 (29) ◽  
pp. 11849-11863 ◽  
Author(s):  
Upendarrao Golla ◽  
Amit Adhikary ◽  
Amit Kumar Mondal ◽  
Raghuvir Singh Tomar ◽  
Sanjit Konar

Three double stranded helicates and one linear chain compound have been synthesized following similar synthetic strategy with change in the coordination of the ligands. Magnetic studies, nuclease activity and cytotoxicity on mammalian cancer cell lines have been investigated.


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