Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes

Hajime Matsushita; Eiichi Negishi

doi:10.1021/ja00400a074

Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes

Journal of the American Chemical Society ◽

10.1021/ja00400a074 ◽

1981 ◽

Vol 103 (10) ◽

pp. 2882-2884 ◽

Cited By ~ 106

Author(s):

Hajime Matsushita ◽

Eiichi Negishi

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. PART 18. PALLADIUM-CATALYZED STEREO- AND REGIOSPECIFIC COUPLING OF ALLYLIC DERIVATIVES WITH ALKENYL- AND ARYLMETALS. A HIGHLY SELECTIVE SYNTHESIS AND 1,4-DIENES

Chemischer Informationsdienst ◽

10.1002/chin.198136144 ◽

1981 ◽

Vol 12 (36) ◽

Author(s):

H. MATSUSHITA ◽

E. NEGISHI

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 20. HIGHLY SELECTIVE SYNTHESIS OF ALLYLATED ARENES AND DIARYLMETHANES VIA PALLADIUM-CATALYZED CROSS COUPLING INVOLVING BENZYLIC DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.198146114 ◽

1981 ◽

Vol 12 (46) ◽

Author(s):

E. NEGISHI ◽

H. MATSUSHITA ◽

N. OKUKADO

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

The Journal of Organic Chemistry ◽

10.1021/jo00430a041 ◽

1977 ◽

Vol 42 (10) ◽

pp. 1821-1823 ◽

Cited By ~ 623

Author(s):

Eiichi Negishi ◽

Anthony O. King ◽

Nobuhisa Okukado

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Aryl Halides ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 3. A HIGHLY SELECTIVE SYNTHESIS OF UNSYMMETRICAL BIARYLS AND DIARYLMETHANES BY THE NICKEL- OR PALLADIUM-CATALYZED REACTION OF ARYL- AND BENZYLZINC DERIVATIVES WITH

Chemischer Informationsdienst ◽

10.1002/chin.197743156 ◽

1977 ◽

Vol 8 (43) ◽

pp. no-no

Author(s):

E. NEGISHI ◽

A. O. KING ◽

N. OKUKADO

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 35. A CONVENIENT SYNTHESIS OF UNSYMMETRICAL BIBENZYLS, HOMOALLYLARENES, AND HOMOPROPARGYLARENES VIA PALLADIUM-CATALYZED CROSS COUPLING

Chemischer Informationsdienst ◽

10.1002/chin.198401180 ◽

1984 ◽

Vol 15 (1) ◽

Author(s):

E. NEGISHI ◽

H. MATSUSHITA ◽

M. KOBAYASHI ◽

C. L. RAND

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Convenient Synthesis ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: CARBOMETALATION. 13. SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 28. A SELECTIVE SYNTHESIS OF ALKENYLMERCURIC CHLORIDES VIA ALKENYLALANES

Chemischer Informationsdienst ◽

10.1002/chin.198243285 ◽

1982 ◽

Vol 13 (43) ◽

Author(s):

E. NEGISHI ◽

K. P. JADHAV ◽

N. DAOTIEN

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 29. A HIGHLY REGIO- AND STEREOSPECIFIC PALLADIUM-CATALYZED ALLYLATION OF ENOLATES DERIVED FROM KETONES

Chemischer Informationsdienst ◽

10.1002/chin.198301170 ◽

1983 ◽

Vol 14 (1) ◽

Author(s):

E. NEGISHI ◽

H. MATSUSHITA ◽

S. CHATTERJEE ◽

R. A. JOHN

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 22. SCOPE OF THE PALLADIUM-CATALYZED COUPLING REACTION OF ORGANOMETALLICS WITH ALLYLIC ELECTROPHILES. EFFECT OF THE LEAVING GROUP

Chemischer Informationsdienst ◽

10.1002/chin.198204135 ◽

1982 ◽

Vol 13 (4) ◽

Author(s):

E.-I. NEGISHI ◽

S. CHATTERJEE ◽

H. MATSUSHITA

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Coupling Reaction ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Leaving Group ◽

Palladium Catalyzed

Download Full-text

Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates

The Journal of Organic Chemistry ◽

10.1021/jo00170a045 ◽

1983 ◽

Vol 48 (22) ◽

pp. 4098-4102 ◽

Cited By ~ 50

Author(s):

Eiichi Negishi ◽

Robert A. John

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text

Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones

The Journal of Organic Chemistry ◽

10.1021/jo00137a038 ◽

1982 ◽

Vol 47 (16) ◽

pp. 3188-3190 ◽

Cited By ~ 78

Author(s):

Eiichi Negishi ◽

Hajime Matsushita ◽

Sugata Chatterjee ◽

Robert A. John

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

Download Full-text