Synthesis and x-ray crystal structure of Mo2(.mu.-t-Bu2P)2(t-Bu2P)2(Mo-Mo); the first structurally characterized binary transition-metal phosphide

1983 ◽  
Vol 105 (19) ◽  
pp. 6184-6185 ◽  
Author(s):  
Richard A. Jones ◽  
Jon G. Lasch ◽  
Nicholas C. Norman ◽  
Bruce R. Whittlesey ◽  
Thomas C. Wright
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Phosphide ◽  
X Ray ◽  
Transition Metal Phosphide

A New Approach to the Synthesis of Transition Metal Phosphide Nanocrystallites (MoP, MoP2, Cu3P and CuP2) by Using Reaction Under Autogenic Pressure at Elevated Temperatures (RAPET) Technique

2016 ◽  
Vol 16 (02) ◽  
pp. 1650030 ◽  
Author(s):  
P. P. George ◽  
I. Genish ◽  
Shirly ben-david Maklouf ◽  
Y. Koltypin ◽  
A. Gedanken
Keyword(s):  
Electron Microscopy ◽  
Transition Metal ◽  
Elevated Temperatures ◽  
Metal Powders ◽  
X Ray Diffraction ◽  
Metal Phosphide ◽  
New Approach ◽  
X Ray ◽  
Transmission Electron ◽  
Transition Metal Phosphide

The reaction under autogenic pressure at elevated temperature (RAPET) technique is proposed for synthesizing a series of metal phosphide nanoparticles such as MoP, MoP2, Cu3P and CuP2 at 850[Formula: see text]C for 3.50[Formula: see text]h by reacting selectively the transition metal powders with elemental phosphorus. The obtained products are characterized by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). A reaction mechanism is suggested based on the experimental results.

scholarly journals Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals

2020 ◽  
Vol 11 (19) ◽  
pp. 5007-5016 ◽  
Author(s):  
Bryan Owens-Baird ◽  
Juliana P. S. Sousa ◽  
Yasmine Ziouani ◽  
Dmitri Y. Petrovykh ◽  
Nikolai A. Zarkevich ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Single Crystals ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Phosphide ◽  
Iron Phosphide ◽  
Transition Metal Phosphide

The effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).

(Invited) Interfacial Chemistry As an Enabling Tool in the Development of Transition Metal Phosphide Electrocatalysts

2021 ◽  
Vol MA2021-01 (39) ◽  
pp. 1286-1286
Author(s):  
Brandi Cossairt ◽  
David Ung ◽  
Ian Murphy ◽  
Ricardo Rivera-Maldonado
Keyword(s):  
Transition Metal ◽  
Interfacial Chemistry ◽  
Metal Phosphide ◽  
Transition Metal Phosphide

The oxygen evolution reaction enabled by transition metal phosphide and chalcogenide pre-catalysts with dynamic changes

2019 ◽  
Vol 55 (60) ◽  
pp. 8744-8763 ◽  
Author(s):  
Wei Li ◽  
Dehua Xiong ◽  
Xuefei Gao ◽  
Lifeng Liu
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Dynamic Changes ◽  
Metal Phosphide ◽  
Electrocatalytic Performance ◽  
Metal Phosphides ◽  
Compositional Changes ◽  
Transition Metal Phosphide ◽  
Transition Metal Phosphides

Dynamic morphological, structural and compositional changes will occur when transition metal phosphides and chalcogenides are used to catalyze the oxygen evolution reaction, which can substantially enhance their electrocatalytic performance.

Mechanisms for hydrogen evolution on transition metal phosphide catalysts and a comparison to Pt(111)

2019 ◽  
Vol 21 (44) ◽  
pp. 24489-24498 ◽  
Author(s):  
Chenyang Li ◽  
Hao Gao ◽  
Wan Wan ◽  
Tim Mueller
Keyword(s):  
Monte Carlo ◽  
Transition Metal ◽  
Monte Carlo Simulations ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Surface Coverage ◽  
Cluster Expansions ◽  
Metal Phosphide ◽  
Transition Metal Phosphide ◽  
Model Transition

Cluster expansions and Monte Carlo simulations provide insights into the mechanisms for the hydrogen evolution reaction and the effects of potential and surface coverage on Pt(111) and model transition metal phosphide surfaces.

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