Formation and thermal reactions of rhodium-carbon bonds derived from the reactions of octaethylporphyrin-rhodium(III) dimer with alkyl carbon-hydrogen bonds in alkyl aromatics

1985 ◽  
Vol 107 (26) ◽  
pp. 7941-7944 ◽  
Author(s):  
Kenneth J. Del Rossi ◽  
Bradford B. Wayland
Keyword(s):  
Hydrogen Bonds ◽  
Thermal Reactions ◽  
Carbon Bonds ◽  
Carbon Hydrogen Bonds

The formation of aromatic hydrocarbons at high temperatures. XXIII. The pyrolysis of anthracene

1964 ◽  
Vol 17 (10) ◽  
pp. 1147 ◽  
Author(s):  
GM Badger ◽  
JK Donnelly ◽  
TM Spotswood
Keyword(s):  
Hydrogen Bonds ◽  
High Temperatures ◽  
Aromatic Hydrocarbons ◽  
Major Constituent ◽  
Polycyclic Hydrocarbons ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
Carbon Hydrogen Bonds

The pyrolysis of anthracene at 700� has given a tar containing ten polycyclic hydrocarbons all of which are probably formed by the scission of carbon-hydrogen bonds to give anthryl radicals followed by further reaction with anthracene. The pyrolysis of anthracene at 950� gave a much more complex tar in which 25 aromatic hydrocarbons have been identified. The major constituent was found to be phenanthrene. It is suggested that this is formed via tetrahydroanthracene and tetrahydrophenanthrene. It is also suggested that the complexity of the tar is due to the scission of the saturated carbon-carbon bonds in tetrahydroanthracene and tetrahydrophenanthrene, followed by further reaction of the fragments.

ChemInform Abstract: Catalytic Formation of Carbon-Carbon Bonds by Activation of Carbon-Hydrogen Bonds

ChemInform ◽  
2010 ◽  
Vol 30 (34) ◽  
pp. no-no
Author(s):  
Yannick Guari ◽  
Sylviane Sabo-Etienne ◽  
Bruno Chaudret
Keyword(s):  
Hydrogen Bonds ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
Carbon Hydrogen Bonds
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