Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

2011 ◽  
Vol 111 (3) ◽  
pp. 1215-1292 ◽  
Author(s):  
Charles S. Yeung ◽  
Vy M. Dong
1964 ◽  
Vol 17 (10) ◽  
pp. 1147 ◽  
Author(s):  
GM Badger ◽  
JK Donnelly ◽  
TM Spotswood

The pyrolysis of anthracene at 700� has given a tar containing ten polycyclic hydrocarbons all of which are probably formed by the scission of carbon-hydrogen bonds to give anthryl radicals followed by further reaction with anthracene. The pyrolysis of anthracene at 950� gave a much more complex tar in which 25 aromatic hydrocarbons have been identified. The major constituent was found to be phenanthrene. It is suggested that this is formed via tetrahydroanthracene and tetrahydrophenanthrene. It is also suggested that the complexity of the tar is due to the scission of the saturated carbon-carbon bonds in tetrahydroanthracene and tetrahydrophenanthrene, followed by further reaction of the fragments.


ChemInform ◽  
2010 ◽  
Vol 30 (34) ◽  
pp. no-no
Author(s):  
Yannick Guari ◽  
Sylviane Sabo-Etienne ◽  
Bruno Chaudret

2018 ◽  
Vol 54 (45) ◽  
pp. 5744-5747 ◽  
Author(s):  
Lingling Zhang ◽  
Guoting Zhang ◽  
Yongli Li ◽  
Shengchun Wang ◽  
Aiwen Lei

Constructing carbon–carbon bonds through oxidative cross-coupling between two hydrocarbon compounds is regarded as a foundational issue in green chemistry.


ChemInform ◽  
2015 ◽  
Vol 46 (10) ◽  
pp. no-no
Author(s):  
Julian C. Lo ◽  
Jinghan Gui ◽  
Yuki Yabe ◽  
Chung-Mao Pan ◽  
Phil S. Baran

2021 ◽  
Author(s):  
Ying Qin ◽  
Lianghui Li ◽  
Jin-Yuan Liang ◽  
Kailong Li ◽  
Dongbing Zhao

Silicon-based cross-coupling has been recognized as one of the most reliable alternatives for constructing carbon−carbon bonds. However, the employment of such reaction as an efficient ring expansion strategy for silacycle...


2015 ◽  
Vol 51 (85) ◽  
pp. 15522-15525 ◽  
Author(s):  
A. L. Stein ◽  
F. N. Bilheri ◽  
G. Zeni

A powerful tool for constructing new carbon–carbon bonds via palladium-catalyzed cross-coupling reactions of unsaturated organoselenides is described.


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