Kinetics of polyatomic free radicals produced by laser photolysis. 5. Study of the equilibrium methyl + oxygen .dblarw. CH3O2 between 421 and 538.degree.

1985 ◽  
Vol 107 (19) ◽  
pp. 5342-5347 ◽  
Author(s):  
Irene R. Slagle ◽  
David Gutman
Keyword(s):  
Free Radicals ◽  
Laser Photolysis ◽  
Kinetics Of

Kinetics of polyatomic free radicals produced by laser photolysis. 4. Study of the equilibrium isopropyl + oxygen .tautm. isopropylperoxy between 592 and 692 K

1985 ◽  
Vol 107 (7) ◽  
pp. 1838-1845 ◽  
Author(s):  
Irene R. Slagle ◽  
Emil Ratajczak ◽  
Michael C. Heaven ◽  
David Gutman ◽  
Albert F. Wagner
Keyword(s):  
Free Radicals ◽  
Laser Photolysis ◽  
Kinetics Of

Kinetics of polyatomic free radicals produced by laser photolysis. 3. Reaction of vinyl radicals with molecular oxygen

1984 ◽  
Vol 106 (16) ◽  
pp. 4356-4361 ◽  
Author(s):  
Irene R. Slagle ◽  
Jong Yoon Park ◽  
Michael C. Heaven ◽  
David Gutman
Keyword(s):  
Free Radicals ◽  
Molecular Oxygen ◽  
Laser Photolysis ◽  
Vinyl Radicals ◽  
Kinetics Of

THE KINETICS OF THE THERMAL REACTIONS OF ETHYLENE OXIDE

1963 ◽  
Vol 41 (12) ◽  
pp. 2956-2961 ◽  
Author(s):  
M. Lynne Neufeld ◽  
Arthur T. Blades
Keyword(s):  
Free Radicals ◽  
Free Radical ◽  
Ethylene Oxide ◽  
Thermal Reactions ◽  
Kinetics Of

The thermal reactions of ethylene oxide in the presence of an excess of propylene have been studied as a function of pressure and it has been found that there are two sets of products, acetaldehyde and free radicals, presumably methyl and formyl. These products are believed to arise from an excited acetaldehyde intermediate. Some evidence has been obtained for the occurrence of a surface-catalyzed rearrangement to acetaldehyde but the free radical products are uninfluenced by surface.

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