Kinetics of polyatomic free radicals produced by laser photolysis. 4. Study of the equilibrium isopropyl + oxygen .tautm. isopropylperoxy between 592 and 692 K

1985 ◽  
Vol 107 (7) ◽  
pp. 1838-1845 ◽  
Author(s):  
Irene R. Slagle ◽  
Emil Ratajczak ◽  
Michael C. Heaven ◽  
David Gutman ◽  
Albert F. Wagner
1984 ◽  
Vol 106 (16) ◽  
pp. 4356-4361 ◽  
Author(s):  
Irene R. Slagle ◽  
Jong Yoon Park ◽  
Michael C. Heaven ◽  
David Gutman

1963 ◽  
Vol 41 (12) ◽  
pp. 2956-2961 ◽  
Author(s):  
M. Lynne Neufeld ◽  
Arthur T. Blades

The thermal reactions of ethylene oxide in the presence of an excess of propylene have been studied as a function of pressure and it has been found that there are two sets of products, acetaldehyde and free radicals, presumably methyl and formyl. These products are believed to arise from an excited acetaldehyde intermediate. Some evidence has been obtained for the occurrence of a surface-catalyzed rearrangement to acetaldehyde but the free radical products are uninfluenced by surface.


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