Kinetics of intermolecular oxidative addition of primary, secondary, and tertiary CH bonds to tricarbonylmanganate anion

Richard N. McDonald; Michael T. Jones

doi:10.1021/ja00285a041

Kinetics of intermolecular oxidative addition of primary, secondary, and tertiary CH bonds to tricarbonylmanganate anion

Journal of the American Chemical Society ◽

10.1021/ja00285a041 ◽

1986 ◽

Vol 108 (25) ◽

pp. 8097-8098 ◽

Cited By ~ 8

Author(s):

Richard N. McDonald ◽

Michael T. Jones

Keyword(s):

Oxidative Addition ◽

Kinetics Of

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Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation

Organometallics ◽

10.1021/om1008499 ◽

2010 ◽

Vol 29 (22) ◽

pp. 6077-6091 ◽

Cited By ~ 45

Author(s):

Jillian A. Hatnean ◽

Robert Beck ◽

Jenna D. Borrelli ◽

Samuel A. Johnson

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Thermodynamics And Kinetics ◽

Kinetics Of

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Kinetics of the oxidative addition of acetone to aromatic compounds under the action of Mn(III) acetate

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00952371 ◽

1982 ◽

Vol 31 (9) ◽

pp. 1760-1765 ◽

Cited By ~ 1

Author(s):

M. G. Vinogradova ◽

R. S. Min ◽

V. S. Aksenov ◽

G. I. Nikishin

Keyword(s):

Aromatic Compounds ◽

Oxidative Addition ◽

Kinetics Of

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The kinetics of oxidative addition of methyl fluorosulphonate to trans-chloro- and to trans-bromo-carbonylbis(triphenylphosphine)iridium(I)

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)82023-9 ◽

1974 ◽

Vol 72 (1) ◽

pp. 121-126 ◽

Cited By ~ 5

Author(s):

J. Burgess ◽

M.J. Hacker ◽

R.D.W. Kemmitt

Keyword(s):

Oxidative Addition ◽

Kinetics Of

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ChemInform Abstract: THE KINETICS OF OXIDATIVE ADDITION OF METHYL FLUOROSULPHONATE TO TRANS-CHLORO- AND TO TRANS-BROMOCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)

Chemischer Informationsdienst ◽

10.1002/chin.197439429 ◽

1974 ◽

Vol 5 (39) ◽

pp. no-no

Author(s):

J. BURGESS ◽

M. J. HACKER ◽

R. D. W. KEMMITT

Keyword(s):

Oxidative Addition ◽

Kinetics Of

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Kinetics of oxidative addition of zerovalent palladium to aromatic iodides

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)86726-1 ◽

1981 ◽

Vol 208 (3) ◽

pp. 419-427 ◽

Cited By ~ 145

Author(s):

Jean-François Fauvarque ◽

Fernando Pflüger ◽

Michel Troupel

Keyword(s):

Oxidative Addition ◽

Kinetics Of

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Activation entropy as a dominant factor in the oxidative addition of some group IV hydrides to an iridium(I) complex

Canadian Journal of Chemistry ◽

10.1139/v76-442 ◽

1976 ◽

Vol 54 (19) ◽

pp. 3102-3109 ◽

Cited By ~ 8

Author(s):

J. P. Fawcett ◽

J. F. Harrod

Keyword(s):

Relative Rate ◽

Oxidative Addition ◽

Group Iv ◽

Dominant Factor ◽

Iridium Complex ◽

Activation Entropy ◽

Acid Base ◽

Square Planar ◽

The Difference ◽

Kinetics Of

The kinetics of the reactions[Formula: see text]have been studied (M = Si, Ge, Sn). All three reactions proceed by predissociation of the iridium complex and concerted cis addition of Ph3MH to the square-planar intermediate. The relative rate of addition of Ph3MH increases in the order Si (1) < Ge (18) < Sn (70) and the difference in rate within experimental error is due entirely to change in ΔS0. It is concluded that, for this particular series of oxidative addition reactions, solvation effects related to a change in polarity on passage to the transition state are more important than bond energies, or acid–base properties, in determining relative reaction energetics. The relevance of entropy barriers to the problem of paraffin activation is discussed.

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