Simplest chloronium radical. A neutralization-reionization mass spectrometry study

1986 ◽  
Vol 108 (18) ◽  
pp. 5656-5657 ◽  
Author(s):  
Chrysostomos. Wesdemiotis ◽  
Rong. Feng ◽  
Fred W. McLafferty
1991 ◽  
Vol 69 (2) ◽  
pp. 363-367
Author(s):  
Guoying Xu ◽  
Jan A. Herman

Ion/molecule reactions in mixtures of ethyl chloride with C1–C4 alkylamines were studied by ICR mass spectrometry. Ethyl cation transfer to C1–C4 alkylamines proceeds mainly through diethylchloronium ions with rate constants ~3 × 10−10cm3 s−1. In the case of s-butylamine the corresponding rate constant is 0.5 × 10−10 cm3 s−1. Key words: ICR mass spectrometry, ion/molecule reactions, ethylchloride, methylamine, ethylamine, propylamines, butylamines


2009 ◽  
Vol 23 (17) ◽  
pp. 2733-2740 ◽  
Author(s):  
Laura Orsatti ◽  
Federica Innocenti ◽  
Paola Lo Surdo ◽  
Fabio Talamo ◽  
Gaetano Barbato

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