Correction. Preparation and Characterization of Stable Ruthenium (IV)-Oxo Complexes Which Contain Tertiary Phosphine Ligands

1986 ◽  
Vol 108 (16) ◽  
pp. 5041-5041
Author(s):  
Mary E. Marmion ◽  
Kenneth J. Takeuchi
Keyword(s):  
Phosphine Ligands ◽  
Tertiary Phosphine ◽  
Oxo Complexes

Preparation and characterization of some ruthenium(II) porphyrins containing tertiary phosphine axial ligands, including the crystal structure of (octaethylporphinato)bis(triphenylphosphine)ruthenium(II)

1984 ◽  
Vol 62 (4) ◽  
pp. 755-762 ◽  
Author(s):  
Sara Ariel ◽  
David Dolphin ◽  
George Domazetis ◽  
Brian R. James ◽  
Tak W. Leung ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Phosphine Ligands ◽  
Tertiary Phosphine ◽  
X Ray ◽  
Porphyrin Complex ◽  
H Nmr ◽  
Axial Ligands ◽  
Nmr Data ◽  
Phosphine Complex

The ruthenium(II) porphyrin complex Ru(OEP)(PPh3)2 (OEP = the dianion of octaethylporphyrin) has been prepared from Ru(OEP)(CO)EtOH, and the X-ray crystal structure determined; as expected, the six-coordinate ruthenium is situated in the porphyrin plane and has two axial phosphine ligands. Synthesized also from the carbonyl(ethanol) precursors were the corresponding tris(p-methoxyphenyl)phosphine complex, and the Ru(TPP)L2 (TPP = the dianion of tetraphenylporphyrin, L = PPh3, P(p-CH3OC6H4)3, P″Bu3) and Ru(TPP)(CO)PPh3 complexes. Optical and 1H nmr data are presented for the complexes in solution. In some cases dissociation of a phosphine ligand to generate five-coordinate species occurs and this has been studied quantitatively in toluene at 20 °C for the Ru(OEP)L2 and Ru(TPP)L2 systems.

Synthesis and characterization of CuI/AuI complexes derived from monothiocarbonate and tertiary phosphine ligands

2017 ◽  
Vol 462 ◽  
pp. 97-105 ◽  
Author(s):  
Jhih-Yu Cyue ◽  
Pilli V.V.N. Kishore ◽  
Jian-Hong Liao ◽  
Yan-Ru Lin ◽  
C.W. Liu
Keyword(s):  
Phosphine Ligands ◽  
Synthesis And Characterization ◽  
Tertiary Phosphine
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