Synthesis and characterization of (nitro)ruthenium complexes that utilize identical trans-positioned tertiary phosphine ligands

Randolph A. Leising; Stephen A. Kubow; Kenneth J. Takeuchi

doi:10.1021/ic00347a047

Synthesis and characterization of (nitro)ruthenium complexes that utilize identical trans-positioned tertiary phosphine ligands

Inorganic Chemistry ◽

10.1021/ic00347a047 ◽

1990 ◽

Vol 29 (22) ◽

pp. 4569-4574 ◽

Cited By ~ 16

Author(s):

Randolph A. Leising ◽

Stephen A. Kubow ◽

Kenneth J. Takeuchi

Keyword(s):

Ruthenium Complexes ◽

Phosphine Ligands ◽

Synthesis And Characterization ◽

Tertiary Phosphine

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Synthesis and characterization of mononuclear ruthenium complexes with carboxylato, chlorido and phosphine ligands. Crystal structures of [RuCl2{κ2-O,O-O2CC CH2(CH3)}(PPh3)2], [RuCl2(κ2-O,O-O2CC6H4-2-Cl)(PPh3)2], and [Et3NH][RuCl(SO2)(κ2-C,O-C6H4-2-CO2)(PPh3)2]

Inorganica Chimica Acta ◽

10.1016/j.ica.2017.06.005 ◽

2017 ◽

Vol 466 ◽

pp. 382-388 ◽

Cited By ~ 1

Author(s):

Jiling Gu ◽

Li-Miao Shi ◽

Xiu-Fang Ma ◽

Ai-Quan Jia ◽

Qian-Feng Zhang

Keyword(s):

Crystal Structures ◽

Ruthenium Complexes ◽

Phosphine Ligands ◽

Synthesis And Characterization

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Synthesis and Characterization of η6-Arene Ruthenium Complexes Bearing Oxopentadienyl and Phosphine Ligands

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.201300104 ◽

2013 ◽

Vol 639 (7) ◽

pp. 1160-1165 ◽

Cited By ~ 6

Author(s):

José Ignacio de la Cruz-Cruz ◽

Julio Cesar Romano-Tequimila ◽

Patricia Juarez-Saavedra ◽

M. Angeles Paz-Sandoval

Keyword(s):

Ruthenium Complexes ◽

Phosphine Ligands ◽

Synthesis And Characterization

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Synthesis and characterization of CuI/AuI complexes derived from monothiocarbonate and tertiary phosphine ligands

Inorganica Chimica Acta ◽

10.1016/j.ica.2017.03.018 ◽

2017 ◽

Vol 462 ◽

pp. 97-105 ◽

Cited By ~ 2

Author(s):

Jhih-Yu Cyue ◽

Pilli V.V.N. Kishore ◽

Jian-Hong Liao ◽

Yan-Ru Lin ◽

C.W. Liu

Keyword(s):

Phosphine Ligands ◽

Synthesis And Characterization ◽

Tertiary Phosphine

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Ruthenium complexes of diphenylphosphino derivatives of carboxylic amides: Synthesis and characterization of bidentate P,N- and P,O-chelate ligands and their reactivity towards [RuCl2(PPh3)3]

Polyhedron ◽

10.1016/j.poly.2016.06.013 ◽

2016 ◽

Vol 120 ◽

pp. 134-141 ◽

Cited By ~ 7

Author(s):

Robert Gericke ◽

Jörg Wagler

Keyword(s):

Ruthenium Complexes ◽

Synthesis And Characterization ◽

Chelate Ligands ◽

Derivatives Of

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Reactions of coordinated dinitrogen. 7. Preparation and characterization of molybdenum bis(dinitrogen) complexes containing mixed tertiary phosphine ligands

Inorganic Chemistry ◽

10.1021/ic50215a061 ◽

1981 ◽

Vol 20 (1) ◽

pp. 285-287 ◽

Cited By ~ 30

Author(s):

T. Adrian. George ◽

Roger A. Kovar

Keyword(s):

Phosphine Ligands ◽

Tertiary Phosphine ◽

Dinitrogen Complexes

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The chemistry of ruthenium complexes of 1,2-dicyanoethylene dithiolate (mnt2–). Synthesis and characterization of [RuIV/III(mnt)3]2–/3– and the derivatives trans-[RuIII(mnt)2(PPh3)2]–, trans-[RuIII(mnt)2(py)2]– and trans-[RuIV(mnt)2(Br)2]2–

Journal of the Chemical Society Dalton Transactions ◽

10.1039/b100603g ◽

2001 ◽

pp. 244-251 ◽

Cited By ~ 3

Author(s):

Rabindranath Maiti ◽

Maoyu Shang ◽

A. Graham Lappin

Keyword(s):

Ruthenium Complexes ◽

Synthesis And Characterization

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Preparation and characterization of some ruthenium(II) porphyrins containing tertiary phosphine axial ligands, including the crystal structure of (octaethylporphinato)bis(triphenylphosphine)ruthenium(II)

Canadian Journal of Chemistry ◽

10.1139/v84-127 ◽

1984 ◽

Vol 62 (4) ◽

pp. 755-762 ◽

Cited By ~ 20

Author(s):

Sara Ariel ◽

David Dolphin ◽

George Domazetis ◽

Brian R. James ◽

Tak W. Leung ◽

...

Keyword(s):

Crystal Structure ◽

Phosphine Ligands ◽

Tertiary Phosphine ◽

X Ray ◽

Porphyrin Complex ◽

H Nmr ◽

Axial Ligands ◽

Nmr Data ◽

Phosphine Complex

The ruthenium(II) porphyrin complex Ru(OEP)(PPh3)2 (OEP = the dianion of octaethylporphyrin) has been prepared from Ru(OEP)(CO)EtOH, and the X-ray crystal structure determined; as expected, the six-coordinate ruthenium is situated in the porphyrin plane and has two axial phosphine ligands. Synthesized also from the carbonyl(ethanol) precursors were the corresponding tris(p-methoxyphenyl)phosphine complex, and the Ru(TPP)L2 (TPP = the dianion of tetraphenylporphyrin, L = PPh3, P(p-CH3OC6H4)3, P″Bu3) and Ru(TPP)(CO)PPh3 complexes. Optical and 1H nmr data are presented for the complexes in solution. In some cases dissociation of a phosphine ligand to generate five-coordinate species occurs and this has been studied quantitatively in toluene at 20 °C for the Ru(OEP)L2 and Ru(TPP)L2 systems.

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