Controlling Photoinduced Electron Transfer within a Hydrogen-Bonded Porphyrin−Phenoxynaphthacenequinone Photochromic System

2001 ◽  
Vol 123 (1) ◽  
pp. 177-178 ◽  
Author(s):  
Andrew J. Myles ◽  
Neil R. Branda
2011 ◽  
Vol 115 (47) ◽  
pp. 23634-23641 ◽  
Author(s):  
Mao-Lin Yu ◽  
Su-Min Wang ◽  
Ke Feng ◽  
Tony Khoury ◽  
Maxwell J. Crossley ◽  
...  

2003 ◽  
Vol 75 (8) ◽  
pp. 1055-1060 ◽  
Author(s):  
Albert M. Brouwer ◽  
Sandro M. Fazio ◽  
Céline Frochot ◽  
Francesco G. Gatti ◽  
David A. Leigh ◽  
...  

Two classes of rotaxanes are described in which photoinduced processes modulate a large-amplitude motion. In the first type, E–Z-isomerization of a fumaric diamide unit to a maleic diamide leads to a substantial weakening of the hydrogen bonds between the diamide and the macrocyclic ring that surrounds it. As a result, the rate of the pirouetting motion is increased approximately by six orders of magnitude. In the second type, intermolecular photoinduced electron transfer is used to induce a reversible shuttling motion on a time scale of microseconds. Medium effects on the rate of shuttling are presented.


2002 ◽  
Vol 124 (35) ◽  
pp. 10252-10253 ◽  
Author(s):  
Albertus P. H. J. Schenning ◽  
Jeroen v. Herrikhuyzen ◽  
Pascal Jonkheijm ◽  
Zhijian Chen ◽  
Frank Würthner ◽  
...  

1992 ◽  
Vol 114 (10) ◽  
pp. 4013-4015 ◽  
Author(s):  
Claudia Turro ◽  
Chi K. Chang ◽  
George E. Leroi ◽  
Robert I. Cukier ◽  
Daniel G. Nocera

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