Photoinduced electron transfer mediated by a hydrogen-bonded interface

1992 ◽  
Vol 114 (10) ◽  
pp. 4013-4015 ◽  
Author(s):  
Claudia Turro ◽  
Chi K. Chang ◽  
George E. Leroi ◽  
Robert I. Cukier ◽  
Daniel G. Nocera
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Bonded Interface ◽  
Hydrogen Bonded

Photoinduced Electron Transfer and Charge-Recombination in 2-Ureido-4[1H]-Pyrimidinone Quadruple Hydrogen-Bonded Porphyrin–Fullerene Assemblies

2011 ◽  
Vol 115 (47) ◽  
pp. 23634-23641 ◽  
Author(s):  
Mao-Lin Yu ◽  
Su-Min Wang ◽  
Ke Feng ◽  
Tony Khoury ◽  
Maxwell J. Crossley ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Charge Recombination ◽  
Hydrogen Bonded

Efficient electron transfer through hydrogen bonded interface

2005 ◽  
Vol 50 (25-26) ◽  
pp. 4857-4860 ◽  
Author(s):  
Slawomir Sek ◽  
Elwira Maicka ◽  
Renata Bilewicz
Keyword(s):  
Electron Transfer ◽  
Bonded Interface ◽  
Hydrogen Bonded

scholarly journals Photoinduced dynamics in hydrogen-bonded rotaxanes

2003 ◽  
Vol 75 (8) ◽  
pp. 1055-1060 ◽  
Author(s):  
Albert M. Brouwer ◽  
Sandro M. Fazio ◽  
Céline Frochot ◽  
Francesco G. Gatti ◽  
David A. Leigh ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Bonds ◽  
Time Scale ◽  
Photoinduced Electron Transfer ◽  
Large Amplitude ◽  
Medium Effects ◽  
Macrocyclic Ring ◽  
Large Amplitude Motion ◽  
Photoinduced Processes ◽  
Hydrogen Bonded

Two classes of rotaxanes are described in which photoinduced processes modulate a large-amplitude motion. In the first type, E–Z-isomerization of a fumaric diamide unit to a maleic diamide leads to a substantial weakening of the hydrogen bonds between the diamide and the macrocyclic ring that surrounds it. As a result, the rate of the pirouetting motion is increased approximately by six orders of magnitude. In the second type, intermolecular photoinduced electron transfer is used to induce a reversible shuttling motion on a time scale of microseconds. Medium effects on the rate of shuttling are presented.

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