Intramolecular activation of aliphatic carbon-hydrogen bonds at tantalum(V) metal centers: a comparison of activation by methyl and methylidene functional groups

Linda R. Chamberlain; Ian P. Rothwell; John C. Huffman

doi:10.1021/ja00267a020

Intramolecular activation of aliphatic carbon-hydrogen bonds at tantalum(V) metal centers: a comparison of activation by methyl and methylidene functional groups

Journal of the American Chemical Society ◽

10.1021/ja00267a020 ◽

1986 ◽

Vol 108 (7) ◽

pp. 1502-1509 ◽

Cited By ~ 64

Author(s):

Linda R. Chamberlain ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Functional Groups ◽

Metal Centers ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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ChemInform Abstract: Intramolecular Activation of Aliphatic Carbon - Hydrogen Bonds at Tantalum(V) Metal Centers: A Comparison of Activation by Methyl and Methylidene Functional Groups.

Chemischer Informationsdienst ◽

10.1002/chin.198630280 ◽

1986 ◽

Vol 17 (30) ◽

Author(s):

L. R. CHAMBERLAIN ◽

I. P. ROTHWELL ◽

J. C. HUFFMAN

Keyword(s):

Hydrogen Bonds ◽

Functional Groups ◽

Metal Centers ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Intramolecular activation of arene carbon-hydrogen bonds by tungsten(II) metal centers and the possible role of metal .pi.-arene intermediates

Organometallics ◽

10.1021/om00108a010 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1431-1438 ◽

Cited By ~ 15

Author(s):

Judith L. Kerschner ◽

Philip E. Fanwick ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Metal Centers ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Intramolecular activation of aliphatic and aromatic carbon-hydrogen bonds by tantalum(III) metal centers: synthesis and structure of the bis-metalated compounds Ta(OC6H3ButCMe2Ch2)2Cl and Ta(OC6H3PhC6H4)2(OAr-2,6-PH2) (OAr-2,6-Ph2 = 2,6-diphenylphenoxide)

Organometallics ◽

10.1021/om00108a008 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1419-1423 ◽

Cited By ~ 16

Author(s):

Bryan D. Steffey ◽

Linda R. Chamberlain ◽

Robert W. Chesnut ◽

Diego E. Chebi ◽

Phillip E. Fanwick ◽

...

Keyword(s):

Hydrogen Bonds ◽

Metal Centers ◽

Aromatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst

Journal of the American Chemical Society ◽

10.1021/ja0291484 ◽

2003 ◽

Vol 125 (6) ◽

pp. 1446-1447 ◽

Cited By ~ 79

Author(s):

Ana Caballero ◽

M. Mar Díaz-Requejo ◽

Tomás R. Belderraín ◽

M. Carmen Nicasio ◽

Swiatoslaw Trofimenko ◽

...

Keyword(s):

Hydrogen Bonds ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds ◽

Regioselective Functionalization

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Intra- and intermolecular activation of sp2 carbon-hydrogen bonds at rhodium(I) and iridium(I) metal centers. X-ray structure of the cis .sigma.-cyclooctadienyl hydride [{N(CH2CH2PPh2)3}IrH(.sigma.-C8H11)]BPh4.cntdot.CH3COCH3

Organometallics ◽

10.1021/om00143a029 ◽

1986 ◽

Vol 5 (12) ◽

pp. 2557-2559 ◽

Cited By ~ 18

Author(s):

Claudio. Bianchini ◽

Dante. Masi ◽

Andrea. Meli ◽

Maurizio. Peruzzini ◽

Michal. Sabat ◽

...

Keyword(s):

Hydrogen Bonds ◽

Metal Centers ◽

X Ray ◽

Carbon Hydrogen Bonds

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ChemInform Abstract: SYNTHESIS OF DI-TERT-BUTYL(CYCLOPROPYLMETHYL)PHOSPHINE, TRANS-PTCL2(P(CME3)2CH2CHCH2CH2)2, AND PTCL(P(CME3)2CH:CMECH2)(P(CME3)2CH2CHCH2CH2). THE INTRAMOLECULAR ACTIVATION OF CARBON-CARBON AND CARBON-HYDROGEN BONDS OF A CYCLOPROPYL PHO

Chemischer Informationsdienst ◽

10.1002/chin.198346319 ◽

1983 ◽

Vol 14 (46) ◽

Author(s):

W. J. YOUNGS ◽

J. A. IBERS

Keyword(s):

Hydrogen Bonds ◽

Tert Butyl ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Reaction of dialkylamido and alkylimido derivatives of molybdenum and tungsten with o-arylphenols: intramolecular activation of aromatic carbon-hydrogen bonds by Mo-NR2 groups

Organometallics ◽

10.1021/om00108a007 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1414-1418 ◽

Cited By ~ 14

Author(s):

Judith L. Kerschner ◽

Joyce S. Yu ◽

Phillip E. Fanwick ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Aromatic Carbon ◽

Carbon Hydrogen Bonds ◽

Derivatives Of ◽

And Tungsten ◽

Intramolecular Activation

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Synthesis of di-tert-butyl(cyclopropylmethyl)phosphine, trans-PtCl2[P(CMe3)2CH2CHCH2CH2]2, and PtCl[P(CMe3)2CH:CMeCH2][P(CMe3)2CH2CHCH2CH2]. The intramolecular activation of carbon-carbon and carbon-hydrogen bonds of a cyclopropyl phosphine

Organometallics ◽

10.1021/om50002a007 ◽

1983 ◽

Vol 2 (8) ◽

pp. 979-985 ◽

Cited By ~ 14

Author(s):

Wiley J. Youngs ◽

James A. Ibers

Keyword(s):

Hydrogen Bonds ◽

Tert Butyl ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Mechanism of activation of carbon-hydrogen bonds in tetramethylsilane and mesitylene and mechanism of intramolecular activation in trimethylphosphine on thermolysis of tetrakis(trimethylphosphine)hydridoneopentylosmium(II)

Journal of the American Chemical Society ◽

10.1021/ja00158a032 ◽

1990 ◽

Vol 112 (2) ◽

pp. 704-713 ◽

Cited By ~ 25

Author(s):

Ronald S. Shinomoto ◽

Peter J. Desrosiers ◽

T. Gregory P. Harper ◽

Thomas C. Flood

Keyword(s):

Hydrogen Bonds ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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ChemInform Abstract: PHOTOINDUCED INSERTION OF TUNGSTEN INTO AROMATIC AND ALIPHATIC CARBON-HYDROGEN BONDS BY BIS(η-CYCLOPENTADIENYL)TUNGSTEN DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.198009322 ◽

1980 ◽

Vol 11 (9) ◽

Author(s):

M. BERRY ◽

K. ELMITT ◽

M. L. H. GREEN

Keyword(s):

Hydrogen Bonds ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds

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