Mechanism of activation of carbon-hydrogen bonds in tetramethylsilane and mesitylene and mechanism of intramolecular activation in trimethylphosphine on thermolysis of tetrakis(trimethylphosphine)hydridoneopentylosmium(II)

Ronald S. Shinomoto; Peter J. Desrosiers; T. Gregory P. Harper; Thomas C. Flood

doi:10.1021/ja00158a032

Mechanism of activation of carbon-hydrogen bonds in tetramethylsilane and mesitylene and mechanism of intramolecular activation in trimethylphosphine on thermolysis of tetrakis(trimethylphosphine)hydridoneopentylosmium(II)

Journal of the American Chemical Society ◽

10.1021/ja00158a032 ◽

1990 ◽

Vol 112 (2) ◽

pp. 704-713 ◽

Cited By ~ 25

Author(s):

Ronald S. Shinomoto ◽

Peter J. Desrosiers ◽

T. Gregory P. Harper ◽

Thomas C. Flood

Keyword(s):

Hydrogen Bonds ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Intramolecular activation of aliphatic carbon-hydrogen bonds at tantalum(V) metal centers: a comparison of activation by methyl and methylidene functional groups

Journal of the American Chemical Society ◽

10.1021/ja00267a020 ◽

1986 ◽

Vol 108 (7) ◽

pp. 1502-1509 ◽

Cited By ~ 64

Author(s):

Linda R. Chamberlain ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Functional Groups ◽

Metal Centers ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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ChemInform Abstract: SYNTHESIS OF DI-TERT-BUTYL(CYCLOPROPYLMETHYL)PHOSPHINE, TRANS-PTCL2(P(CME3)2CH2CHCH2CH2)2, AND PTCL(P(CME3)2CH:CMECH2)(P(CME3)2CH2CHCH2CH2). THE INTRAMOLECULAR ACTIVATION OF CARBON-CARBON AND CARBON-HYDROGEN BONDS OF A CYCLOPROPYL PHO

Chemischer Informationsdienst ◽

10.1002/chin.198346319 ◽

1983 ◽

Vol 14 (46) ◽

Author(s):

W. J. YOUNGS ◽

J. A. IBERS

Keyword(s):

Hydrogen Bonds ◽

Tert Butyl ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Reaction of dialkylamido and alkylimido derivatives of molybdenum and tungsten with o-arylphenols: intramolecular activation of aromatic carbon-hydrogen bonds by Mo-NR2 groups

Organometallics ◽

10.1021/om00108a007 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1414-1418 ◽

Cited By ~ 14

Author(s):

Judith L. Kerschner ◽

Joyce S. Yu ◽

Phillip E. Fanwick ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Aromatic Carbon ◽

Carbon Hydrogen Bonds ◽

Derivatives Of ◽

And Tungsten ◽

Intramolecular Activation

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Synthesis of di-tert-butyl(cyclopropylmethyl)phosphine, trans-PtCl2[P(CMe3)2CH2CHCH2CH2]2, and PtCl[P(CMe3)2CH:CMeCH2][P(CMe3)2CH2CHCH2CH2]. The intramolecular activation of carbon-carbon and carbon-hydrogen bonds of a cyclopropyl phosphine

Organometallics ◽

10.1021/om50002a007 ◽

1983 ◽

Vol 2 (8) ◽

pp. 979-985 ◽

Cited By ~ 14

Author(s):

Wiley J. Youngs ◽

James A. Ibers

Keyword(s):

Hydrogen Bonds ◽

Tert Butyl ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexes

Chemical Reviews ◽

10.1021/cr00100a004 ◽

1990 ◽

Vol 90 (2) ◽

pp. 403-424 ◽

Cited By ~ 765

Author(s):

Alexander D. Ryabov

Keyword(s):

Transition Metal ◽

Hydrogen Bonds ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Intramolecular activation of arene carbon-hydrogen bonds by tungsten(II) metal centers and the possible role of metal .pi.-arene intermediates

Organometallics ◽

10.1021/om00108a010 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1431-1438 ◽

Cited By ~ 15

Author(s):

Judith L. Kerschner ◽

Philip E. Fanwick ◽

Ian P. Rothwell ◽

John C. Huffman

Keyword(s):

Hydrogen Bonds ◽

Metal Centers ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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ChemInform Abstract: Intramolecular Activation of Aliphatic Carbon - Hydrogen Bonds at Tantalum(V) Metal Centers: A Comparison of Activation by Methyl and Methylidene Functional Groups.

Chemischer Informationsdienst ◽

10.1002/chin.198630280 ◽

1986 ◽

Vol 17 (30) ◽

Author(s):

L. R. CHAMBERLAIN ◽

I. P. ROTHWELL ◽

J. C. HUFFMAN

Keyword(s):

Hydrogen Bonds ◽

Functional Groups ◽

Metal Centers ◽

Aliphatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Intramolecular activation of aliphatic and aromatic carbon-hydrogen bonds by tantalum(III) metal centers: synthesis and structure of the bis-metalated compounds Ta(OC6H3ButCMe2Ch2)2Cl and Ta(OC6H3PhC6H4)2(OAr-2,6-PH2) (OAr-2,6-Ph2 = 2,6-diphenylphenoxide)

Organometallics ◽

10.1021/om00108a008 ◽

1989 ◽

Vol 8 (6) ◽

pp. 1419-1423 ◽

Cited By ~ 16

Author(s):

Bryan D. Steffey ◽

Linda R. Chamberlain ◽

Robert W. Chesnut ◽

Diego E. Chebi ◽

Phillip E. Fanwick ◽

...

Keyword(s):

Hydrogen Bonds ◽

Metal Centers ◽

Aromatic Carbon ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Effect of fluorine substituents in intramolecular activation of carbon-fluorine and carbon-hydrogen bonds by platinum(II)

Organometallics ◽

10.1021/om00035a014 ◽

1993 ◽

Vol 12 (11) ◽

pp. 4297-4304 ◽

Cited By ~ 64

Author(s):

Margarita Crespo ◽

Manuel Martinez ◽

Joaquim Sales

Keyword(s):

Hydrogen Bonds ◽

Carbon Hydrogen Bonds ◽

Intramolecular Activation

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Catalytic functionalization of carbon-hydrogen bonds by isonitrile insertion. Preparation, characterization, and reactivity of RhCl(PR3)2(CNR')

Organometallics ◽

10.1021/om00117a030 ◽

1990 ◽

Vol 9 (3) ◽

pp. 718-727 ◽

Cited By ~ 41

Author(s):

William D. Jones ◽

Edward T. Hessell

Keyword(s):

Hydrogen Bonds ◽

Carbon Hydrogen Bonds ◽

Catalytic Functionalization

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