Photoelectron spectroscopy with variable photon energy. A study of the metal hexacarbonyls M(CO)6 where M = Cr, Mo, and W

1987 ◽  
Vol 109 (13) ◽  
pp. 3836-3843 ◽  
Author(s):  
Glyn Cooper ◽  
Jennifer C. Green ◽  
Martin P. Payne ◽  
Barry R. Dobson ◽  
Ian H. Hillier
Keyword(s):  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Metal Hexacarbonyls

Evidence for the Photoemission Nature of Gd 4f Resonant Photoemission

1998 ◽  
Vol 524 ◽  
Author(s):  
S. R. Mishra ◽  
T. R. Cummins ◽  
W. J. Gammon ◽  
G. D. Waddill ◽  
G. Van der-Laan ◽  
...  
Keyword(s):  
Angular Distribution ◽  
Cross Section ◽  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Emission Cross Section ◽  
Linear Dichroism ◽  
Constructive Interference ◽  
Resonant Photoemission ◽  
Magnetic Linear Dichroism ◽  
Spectroscopy Experiment

ABSTRACTThe constructive interference between direct and indirect channels above the absorption threshold of a core level leads to a massive increase in the emission cross section leading to a phenomenon called “resonant photoemission”. Using novel magnetic linear dichroism in angular distribution photoelectron spectroscopy experiment we have tried to understand the nature of the resonant photoemission process in Gd metal. The presence of dichroism in Gd 4f photoemission intensity at a photon energy corresponding to resonant photoemission clearly demonstrates the photoemission-like nature of the resonant photoemission process.

The electronic nature of the metal-metal quadruple bond: variable photon energy photoelectron spectroscopy of Mo2(O2CCH3)4

1992 ◽  
Vol 114 (26) ◽  
pp. 10492-10497 ◽  
Author(s):  
Dennis L. Lichtenberger ◽  
Charles D. Ray ◽  
Frank Stepniak ◽  
Yu Chen ◽  
J. H. Weaver
Keyword(s):  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Electronic Nature ◽  
Quadruple Bond ◽  
Metal Metal

Angle-resolved photoelectron study of the group VIB metal hexacarbonyls M(CO)6 (M=Cr, Mo, W) from 9 to 30 eV photon energy

1990 ◽  
Vol 147 (2-3) ◽  
pp. 431-436 ◽  
Author(s):  
B.W. Yates ◽  
G.A. von Wald ◽  
J.W. Taylor ◽  
F.A. Grimm ◽  
J.S. Tse
Keyword(s):  
Photon Energy ◽  
Photoelectron Study ◽  
Metal Hexacarbonyls

PHOTOELECTRON SPECTROSCOPY OF SILICON–CARBON CLUSTER ANIONS

1996 ◽  
Vol 03 (01) ◽  
pp. 411-415 ◽  
Author(s):  
A. NAKAJIMA ◽  
T. TAGUWA ◽  
K. NAKAO ◽  
M. GOMEI ◽  
R. KISHI ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Carbon Cluster ◽  
Photoelectron Spectra ◽  
Laser Vaporization ◽  
Cluster Anions ◽  
Electron Spectrometer ◽  
Silicon Carbon ◽  
Magnetic Bottle

Photoelectron spectra of [Formula: see text] cluster anions (3≤n, m≤6) were measured at the photon energy of 3.49 eV, by using a magnetic-bottle electron spectrometer having ~60-meV resolution. The [Formula: see text] clusters were produced by laser vaporization of a carbon–silicon mixture rod in a He carrier gas. The spectra of the [Formula: see text] clusters are similar to those of pure [Formula: see text] clusters in the peak positions and their envelopes, which is attributed to the similarity in electronic structure of Si and C atoms, leading to a similar geometry. In contrast, the similarity in the photoelectron spectra is not observed between [Formula: see text] and [Formula: see text] clusters, which is attributed to a change in their geometry; from chain to ring.

Angle‐resolved photoelectron spectroscopy of the valence orbitals of SiCl4 as a function of photon energy from 14 to 80 eV

1986 ◽  
Vol 84 (2) ◽  
pp. 641-648 ◽  
Author(s):  
Thomas A. Carlson ◽  
Anders Fahlman ◽  
Manfred O. Krause ◽  
Timothy A. Whitley ◽  
Frederick A. Grimm ◽  
...  
Keyword(s):  
Photon Energy ◽  
Photoelectron Spectroscopy

Angle resolved photoelectron spectroscopy of the valence shells in HI and CH3I as a function of photon energy from 13 to 90 eV

1984 ◽  
Vol 80 (8) ◽  
pp. 3521-3527 ◽  
Author(s):  
Thomas A. Carlson ◽  
Anders Fahlman ◽  
Manfred O. Krause ◽  
Paul R. Keller ◽  
James W. Taylor ◽  
...  
Keyword(s):  
Photon Energy ◽  
Photoelectron Spectroscopy
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