Nature of the Cycloheptatrienyl-Transition Metal Bond. A Study of Electron Distribution in the Mixed-Ring Sandwich Molecules [Ti(.eta.-C7H7)(.eta.-C5H5)], [Nb(.eta.-C7H7)(.eta.-C5H5)], [Ta(.eta.-C7H7)(.eta.-C5H4Me)], and [Mo(.eta.-C7H7)(.eta.-C5H5)] by Photoelectron Spectroscopy with Variable Photon Energy

1994 ◽  
Vol 116 (5) ◽  
pp. 1994-2004 ◽  
Author(s):  
Jennifer C. Green ◽  
Nikolas Kaltsoyannis ◽  
Kong Hung Sze ◽  
Michael MacDonald
Keyword(s):  
Transition Metal ◽  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Electron Distribution ◽  
Metal Bond

scholarly journals Determination of the electron distribution in a transition metal carbene complex by x-ray photoelectron spectroscopy

1974 ◽  
Vol 13 (8) ◽  
pp. 2038-2039 ◽  
Author(s):  
Winfield B. Perry ◽  
Theodore F. Schaaf ◽  
William L. Jolly ◽  
Lee J. Todd ◽  
David L. Cronin
Keyword(s):  
Transition Metal ◽  
Photoelectron Spectroscopy ◽  
Electron Distribution ◽  
X Ray ◽  
Carbene Complex

Evidence for the Photoemission Nature of Gd 4f Resonant Photoemission

1998 ◽  
Vol 524 ◽  
Author(s):  
S. R. Mishra ◽  
T. R. Cummins ◽  
W. J. Gammon ◽  
G. D. Waddill ◽  
G. Van der-Laan ◽  
...  
Keyword(s):  
Angular Distribution ◽  
Cross Section ◽  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Emission Cross Section ◽  
Linear Dichroism ◽  
Constructive Interference ◽  
Resonant Photoemission ◽  
Magnetic Linear Dichroism ◽  
Spectroscopy Experiment

ABSTRACTThe constructive interference between direct and indirect channels above the absorption threshold of a core level leads to a massive increase in the emission cross section leading to a phenomenon called “resonant photoemission”. Using novel magnetic linear dichroism in angular distribution photoelectron spectroscopy experiment we have tried to understand the nature of the resonant photoemission process in Gd metal. The presence of dichroism in Gd 4f photoemission intensity at a photon energy corresponding to resonant photoemission clearly demonstrates the photoemission-like nature of the resonant photoemission process.

The electronic nature of the metal-metal quadruple bond: variable photon energy photoelectron spectroscopy of Mo2(O2CCH3)4

1992 ◽  
Vol 114 (26) ◽  
pp. 10492-10497 ◽  
Author(s):  
Dennis L. Lichtenberger ◽  
Charles D. Ray ◽  
Frank Stepniak ◽  
Yu Chen ◽  
J. H. Weaver
Keyword(s):  
Photon Energy ◽  
Photoelectron Spectroscopy ◽  
Electronic Nature ◽  
Quadruple Bond ◽  
Metal Metal

On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

2010 ◽  
Vol 39 (44) ◽  
pp. 10588 ◽  
Author(s):  
Clara J. Durango-García ◽  
J. Oscar C. Jiménez-Halla ◽  
Marcela López-Cardoso ◽  
Virginia Montiel-Palma ◽  
Miguel A. Muñoz-Hernández ◽  
...  
Keyword(s):  
Transition Metal ◽  
Theoretical Calculations ◽  
Main Group ◽  
Metal Bond ◽  
Group Metal ◽  
Main Group Metal
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