Proton NMR study of the electronic and molecular structure of the heme cavity in horseradish peroxidase. Complete heme resonance assignments based on saturation transfer and nuclear Overhauser effects

V. Thanabal; Jeffrey S. DeRopp; Gerd N. La Mar

doi:10.1021/ja00235a040

Proton NMR study of the electronic and molecular structure of the heme cavity in horseradish peroxidase. Complete heme resonance assignments based on saturation transfer and nuclear Overhauser effects

Journal of the American Chemical Society ◽

10.1021/ja00235a040 ◽

1987 ◽

Vol 109 (1) ◽

pp. 265-272 ◽

Cited By ~ 78

Author(s):

V. Thanabal ◽

Jeffrey S. DeRopp ◽

Gerd N. La Mar

Keyword(s):

Molecular Structure ◽

Horseradish Peroxidase ◽

Proton Nmr ◽

Resonance Assignments ◽

Saturation Transfer ◽

Nmr Study ◽

Nuclear Overhauser ◽

Nuclear Overhauser Effects

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500-MHz proton NMR study of poly(dG).cntdot.poly(dC) in solution using one-dimensional nuclear Overhauser effect

Biochemistry ◽

10.1021/bi00360a028 ◽

1986 ◽

Vol 25 (12) ◽

pp. 3659-3665 ◽

Cited By ~ 30

Author(s):

Mukti H. Sarma ◽

Goutam Gupta ◽

Ramaswamy H. Sarma

Keyword(s):

Nuclear Overhauser Effect ◽

Proton Nmr ◽

One Dimensional ◽

Overhauser Effect ◽

Nmr Study ◽

Nuclear Overhauser

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Solution NMR Study of the Electronic and Molecular Structure of the Heme Cavity in High-Spin, Resting State Horseradish Peroxidase

Journal of the American Chemical Society ◽

10.1021/ja9642018 ◽

1997 ◽

Vol 119 (20) ◽

pp. 4732-4739 ◽

Cited By ~ 26

Author(s):

Jeffrey S. de Ropp ◽

Pravat Mandal ◽

Samuel L. Brauer ◽

Gerd N. La Mar

Keyword(s):

Molecular Structure ◽

Horseradish Peroxidase ◽

High Spin ◽

Resting State ◽

Solution Nmr ◽

Nmr Study

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An NMR study of the interaction between the antibiotic ristocetin A and a cell wall peptide analog. Negative nuclear Overhauser effects in the investigation of drug binding sites

Journal of the American Chemical Society ◽

10.1021/ja00523a002 ◽

1980 ◽

Vol 102 (3) ◽

pp. 906-912 ◽

Cited By ~ 37

Author(s):

John R. Kalman ◽

Dudley H. Williams

Keyword(s):

Cell Wall ◽

Binding Sites ◽

Drug Binding ◽

Peptide Analog ◽

Nmr Study ◽

Ristocetin A ◽

A Cell ◽

Drug Binding Sites ◽

Nuclear Overhauser ◽

Nuclear Overhauser Effects

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Assignment of the low-field proton NMR spectrum of Escherichia coli tRNAPhe using nuclear Overhauser effects

Biochemistry ◽

10.1021/bi00337a009 ◽

1985 ◽

Vol 24 (16) ◽

pp. 4307-4314 ◽

Cited By ~ 19

Author(s):

Eva I. Hyde ◽

Brian R. Reid

Keyword(s):

Escherichia Coli ◽

Proton Nmr ◽

Nmr Spectrum ◽

Low Field ◽

Nuclear Overhauser ◽

Nuclear Overhauser Effects

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Nuclear Overhauser effects and the assignment of the proton NMR spectra of proteins

FEBS Letters ◽

10.1016/0014-5793(84)81185-0 ◽

1984 ◽

Vol 176 (2) ◽

pp. 307-312 ◽

Cited By ~ 7

Author(s):

Christopher M. Dobson ◽

Martin A. Howarth ◽

Christina Redfield

Keyword(s):

Nmr Spectra ◽

Proton Nmr ◽

Nuclear Overhauser ◽

Nuclear Overhauser Effects

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ChemInform Abstract: APPLICATIONS OF NUCLEAR OVERHAUSER EFFECTS. III. PROTON NMR SPECTRA AND THE NUCLEAR OVERHAUSER EFFECT IN E AND Z ISOMERS OF 3-SUBSTITUTED 3-AMINOACRYLONITRILES

Chemischer Informationsdienst ◽

10.1002/chin.197605040 ◽

1976 ◽

Vol 7 (5) ◽

pp. no-no

Author(s):

J. DEDINA ◽

J. KUTHAN ◽

J. PALECEK ◽

J. SCHRAML

Keyword(s):

Nmr Spectra ◽

Nuclear Overhauser Effect ◽

Proton Nmr ◽

Overhauser Effect ◽

E And Z Isomers ◽

Nuclear Overhauser ◽

Nuclear Overhauser Effects

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ChemInform Abstract: LOW-TEMPERATURE CRYSTAL AND MOLECULAR STRUCTURE OF TETRACARBONYL(2-BROMOHEPTAHYDROTRIBORATO(1-))MANGANESE, (CO)4MNB3H7BR, AND A PROTON NMR STUDY OF THE KINETICS OF ITS INTRAMOLECULAR HYDROGEN EXCHANGE IN SOLUTION

Chemischer Informationsdienst ◽

10.1002/chin.198043044 ◽

1980 ◽

Vol 11 (43) ◽

Author(s):

M. W. CHEN ◽

J. C. CALABRESE ◽

D. F. GAINES ◽

D. F. HILLENBRAND

Keyword(s):

Molecular Structure ◽

Low Temperature ◽

Hydrogen Exchange ◽

Crystal And Molecular Structure ◽

Proton Nmr ◽

Nmr Study ◽

Intramolecular Hydrogen ◽

Kinetics Of

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NMR study of the molecular and electronic structure of the heme cavity of Aplysia metmyoglobin. Resonance assignments based on isotope labeling and proton nuclear Overhauser effect measurements

Biochemistry ◽

10.1021/bi00367a044 ◽

1986 ◽

Vol 25 (19) ◽

pp. 5638-5646 ◽

Cited By ~ 45

Author(s):

Usha Pande ◽

Gerd N. La Mar ◽

Juliette T. J. Lecomte ◽

Franca Ascoli ◽

Maurizio Brunori ◽

...

Keyword(s):

Electronic Structure ◽

Isotope Labeling ◽

Nuclear Overhauser Effect ◽

Resonance Assignments ◽

Overhauser Effect ◽

Nmr Study ◽

Nuclear Overhauser ◽

Molecular And Electronic Structure

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A dynamic NMR study of the nitrogen lone pair orientation in 2-benzoyl-5-methyl-5-aza-1,3-dithiacyclohexane

Canadian Journal of Chemistry ◽

10.1139/v89-321 ◽

1989 ◽

Vol 67 (12) ◽

pp. 2067-2070 ◽

Cited By ~ 6

Author(s):

B. Mario Pinto ◽

Blair D. Johnston ◽

Ruby Nagelkerke ◽

Eusebio Juaristi ◽

Eduardo A. González

Keyword(s):

Magnetization Transfer ◽

Lone Pair ◽

Anomeric Effect ◽

Saturation Transfer ◽

Nuclear Overhauser Enhancement ◽

Free Energy Of Activation ◽

Nmr Study ◽

Nitrogen Lone Pair ◽

Nuclear Overhauser ◽

Related Compounds

Nuclear Overhauser enhancement difference experiments and magnetization transfer experiments on 2-benzoyl-5-methyl-5-aza-1,3-dithiacyclohexane 1 at 186 K show conclusively that the N-methyl group adopts a preferred axial orientation. The result has implications for evaluation of the origin of the anomeric effect in this and related compounds. The free energy of activation for ring interconversion in 1 is estimated by spin saturation transfer experiments to be 10.7 ± 0.4 kcal mol−1. Keywords: D NMR, conformational analysis, nuclear Overhauser enhancement, saturation transfer.

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