Kinetics of the anion-catalyzed Michael reaction of silyl ketene acetals. Initiation and propagation steps of group transfer polymerization

1988 ◽  
Vol 110 (22) ◽  
pp. 7440-7444 ◽  
Author(s):  
William J. Brittain
Keyword(s):  
Michael Reaction ◽  
Group Transfer ◽  
Initiation And Propagation ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals ◽  
Kinetics Of

scholarly journals The Catalytic Asymmetric Mukaiyama-Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

2018 ◽  
Vol 57 (9) ◽  
pp. 2464-2468 ◽  
Author(s):  
Tim Gatzenmeier ◽  
Philip S. J. Kaib ◽  
Julia B. Lingnau ◽  
Richard Goddard ◽  
Benjamin List
Keyword(s):  
Michael Reaction ◽  
Methyl Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals ◽  
Catalytic Asymmetric

Controlled or High-Speed Group Transfer Polymerization by Silyl Ketene Acetals without Catalyst

2016 ◽  
Vol 49 (21) ◽  
pp. 8075-8087 ◽  
Author(s):  
Jiawei Chen ◽  
Ravikumar R. Gowda ◽  
Jianghua He ◽  
Yuetao Zhang ◽  
Eugene Y.-X. Chen
Keyword(s):  
High Speed ◽  
Group Transfer ◽  
Speed Group ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

Synthesis of end-functionalized poly(methyl methacrylate) by organocatalyzed group transfer polymerization using functional silyl ketene acetals and α-phenylacrylates

2015 ◽  
Vol 6 (10) ◽  
pp. 1830-1837 ◽  
Author(s):  
Yougen Chen ◽  
Kenji Takada ◽  
Naoya Kubota ◽  
Ofosu-Twum Eric ◽  
Takahiro Ito ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Group Transfer ◽  
Poly Methyl Methacrylate ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

The α and ω-end-functionalization of PMMA by organocatalyzed GTP was achieved using functional silyl ketene acetals and α-phenylacrylates.

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