Isomerization of silyl ketene acetals: Models for the propagating chain end in group transfer polymerization

1993 ◽  
Vol 30 (1) ◽  
pp. 101-107 ◽  
Author(s):  
William J. Brittain ◽  
Ira B. Dicker
Keyword(s):  
Group Transfer ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

Controlled or High-Speed Group Transfer Polymerization by Silyl Ketene Acetals without Catalyst

2016 ◽  
Vol 49 (21) ◽  
pp. 8075-8087 ◽  
Author(s):  
Jiawei Chen ◽  
Ravikumar R. Gowda ◽  
Jianghua He ◽  
Yuetao Zhang ◽  
Eugene Y.-X. Chen
Keyword(s):  
High Speed ◽  
Group Transfer ◽  
Speed Group ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

Synthesis of end-functionalized poly(methyl methacrylate) by organocatalyzed group transfer polymerization using functional silyl ketene acetals and α-phenylacrylates

2015 ◽  
Vol 6 (10) ◽  
pp. 1830-1837 ◽  
Author(s):  
Yougen Chen ◽  
Kenji Takada ◽  
Naoya Kubota ◽  
Ofosu-Twum Eric ◽  
Takahiro Ito ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Group Transfer ◽  
Poly Methyl Methacrylate ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

The α and ω-end-functionalization of PMMA by organocatalyzed GTP was achieved using functional silyl ketene acetals and α-phenylacrylates.

Synthesis of Reactive-Ended Acrylic Polymers by Group Transfer Polymerization: Initiation with Silyl Ketene Acetals

1984 ◽  
Vol 21 (8-9) ◽  
pp. 943-960 ◽  
Author(s):  
O. W. Webster ◽  
W. R. Hertler ◽  
D. Y. Sogah ◽  
W. B. Farnhara ◽  
T. V. Rajanbabu
Keyword(s):  
Acrylic Polymers ◽  
Group Transfer ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

Lewis Base Activation of Lewis Acids. Addition of Silyl Ketene Acetals to Aldehydes

2002 ◽  
Vol 124 (45) ◽  
pp. 13405-13407 ◽  
Author(s):  
Scott E. Denmark ◽  
Thomas Wynn ◽  
Gregory L. Beutner
Keyword(s):  
Lewis Acids ◽  
Lewis Base ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals
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