Toward New Electronic, Magnetic, and Optical Materials: Structure and Properties of the First Homobimetallic Tetrathiafulvalene Tetrathiolate Building Block

1995 ◽  
Vol 117 (39) ◽  
pp. 9913-9914 ◽  
Author(s):  
Richard D. McCullough ◽  
John A. Belot ◽  
Arnold L. Rheingold ◽  
Glen P. A. Yap
Keyword(s):  
Building Block ◽  
Optical Materials ◽  
Structure And Properties

scholarly journals Modulating structure and properties in organic chromophores: influence of azulene as a building block

2014 ◽  
Vol 5 (10) ◽  
pp. 3753-3760 ◽  
Author(s):  
Masahito Murai ◽  
Sung-Yu Ku ◽  
Neil D. Treat ◽  
Maxwell J. Robb ◽  
Michael L. Chabinyc ◽  
...  
Keyword(s):  
Building Block ◽  
Theoretical Calculations ◽  
Membered Ring ◽  
Structure And Properties ◽  
Organic Chromophores

The properties of isomeric azulene derivatives, substituted through the 5-membered ring, were examined using a combination of experimentation and theoretical calculations for a series of well-defined electroactive oligomers.

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials

2012 ◽  
Vol 51 (10) ◽  
pp. 5839-5843 ◽  
Author(s):  
Wenlong Yin ◽  
Kai Feng ◽  
Wenyu Hao ◽  
Jiyong Yao ◽  
Yicheng Wu
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Nonlinear Optical Materials ◽  
Structure And Properties

ChemInform Abstract: The Synthesis, Structure and Properties of a New Compound with 1D Linear Chain Arsenomolybdate Anion Building Block.

ChemInform ◽  
2016 ◽  
Vol 47 (1) ◽  
Author(s):  
Wenqi Zhao ◽  
Zhanhua Su ◽  
Zhifeng Zhao ◽  
Bowen Cong ◽  
Lin Xia ◽  
...  
Keyword(s):  
Building Block ◽  
Linear Chain ◽  
Structure And Properties

scholarly journals Single-molecule magnet engineering: building-block approaches

2014 ◽  
Vol 50 (34) ◽  
pp. 4396-4415 ◽  
Author(s):  
Kasper S. Pedersen ◽  
Jesper Bendix ◽  
Rodolphe Clérac
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Building Blocks ◽  
Structure And Properties ◽  
Feature Article ◽  
Single Molecule Magnet

This Feature article focuses on the use ofbuilding-blocksto direct structure and properties of complexes exhibiting single-molecule magnet behavior.

Crystal Growth, Structure, and Properties of New Nonlinear Optical Materials: K2Ln(NO3)5·2H2O (Ln=La, Ce, Pr, Nd, Sm)

1999 ◽  
Vol 148 (2) ◽  
pp. 302-307 ◽  
Author(s):  
Wenting Dong ◽  
Hongjie Zhang ◽  
Qiang Su ◽  
Yonghua Lin ◽  
Shumei Wang ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Nonlinear Optical Materials ◽  
Structure And Properties ◽  
Growth Structure

scholarly journals Structure, physical and chemical properties of near-surface layers of optical materials modified by treatment in hydrogen plasma

2021 ◽  
pp. 12-39
Author(s):  
U. O. Salgaeva ◽  
◽  
A. B. Volyntsev ◽  
S. S. Mushinsky ◽  
◽  
...  
Keyword(s):  
Optical Materials ◽  
Hydrogen Plasma ◽  
Surface Region ◽  
Soda Lime ◽  
Plasma Modification ◽  
Soda Lime Glass ◽  
Structure And Properties ◽  
Surface Layers ◽  
Near Surface ◽  
First Time

The present paper aims to investigate the structure and properties of the near-surface layers of optical materials modified by treatment in hydrogen plasma (H-plasma). For this the quartz and soda-lime glasses, lithium niobate (LN) as delivered and LN after proton exchange were used. The structure and properties of the near-surface layers of optical materials were investigated by IR spectroscopy, Raman spectroscopy, X-ray diffraction analysis, atomic force microscopy, mode spectroscopy, scanning electron microscopy, and wet chemical etching. During the treatment in H-plasma the hydrogen penetrated into the near-surface layers and caused increasing the number of defects in the structure of materials. Changes of the shape and intensity of the absorption peaks of OH–-groups and the θ/2θ- curves recorded from the LN samples processed in H-plasma were inconsequent, probably due to the thin modified layer. For the first time, a huge volume “swelling” (above 10 %) of the near-surface layers of LN and soda-lime glass after the processing in H-plasma was revealed. Also for the first time, the formation of thin strained layers on the surface of the LN after treatment in H-plasma was shown; the density reduction of the near-surface layers of the LN modified in H-plasma was described; the features of blistering and flaking were found on the surface of LN and soda-lime glass after their treatment for a long time (120–150 min). For the first time, the multilayer structure of the near-surface region of the LN was detected after treatment in H-plasma. In this paper we proposed the model of changes the structure and properties of LN after the treatment in H-plasma. The model explains the experimental results obtained in this study and previously published studies of other research groups. Due to the high concentration in the near-surface layers of optical materials after the H-plasma treatment, hydrogen predominantly forms pores and bubbles. Presumably the compounds of the Li2O–Nb2O5 system with a low Li content formed in the near-surface region of LN after the treatment in H-plasma. Modification of near-surface layers of optical materials in hydrogen plasma could be used to form elements of integrated-optical circuits, particularly the diffraction gratings.

The synthesis, structure and properties of a new compound with 1D linear chain arsenomolybdate anion building block

2015 ◽  
Vol 61 ◽  
pp. 118-122 ◽  
Author(s):  
Wenqi Zhao ◽  
Zhanhua Su ◽  
Zhifeng Zhao ◽  
Bowen Cong ◽  
Lin Xia ◽  
...  
Keyword(s):  
Building Block ◽  
Linear Chain ◽  
Structure And Properties
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