scholarly journals Single-molecule magnet engineering: building-block approaches

2014 ◽  
Vol 50 (34) ◽  
pp. 4396-4415 ◽  
Author(s):  
Kasper S. Pedersen ◽  
Jesper Bendix ◽  
Rodolphe Clérac
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Building Blocks ◽  
Structure And Properties ◽  
Feature Article ◽  
Single Molecule Magnet

This Feature article focuses on the use ofbuilding-blocksto direct structure and properties of complexes exhibiting single-molecule magnet behavior.

ChemInform Abstract: Single-Molecule Magnet Engineering: Building-Block Approaches

ChemInform ◽  
2014 ◽  
Vol 45 (24) ◽  
pp. no-no
Author(s):  
Kasper S. Pedersen ◽  
Jesper Bendix ◽  
Rodolphe Clerac
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Single Molecule Magnet

Single-molecule magnet behavior in an octanuclear dysprosium(iii) aggregate inherited from helical triangular Dy3 SMM-building blocks

2016 ◽  
Vol 45 (26) ◽  
pp. 10556-10562 ◽  
Author(s):  
Li Zhang ◽  
Peng Zhang ◽  
Lang Zhao ◽  
Jianfeng Wu ◽  
Mei Guo ◽  
...  
Keyword(s):  
Single Molecule ◽  
Building Blocks ◽  
Single Molecule Magnet

A novel supramolecular octanuclear dysprosium(iii) cluster coupling two original helical Dy3 SMM-building blocks is isolated and shows typical SMM behavior under zero dc field inherited from its Dy3 helical precursor.

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

An Organometallic Building Block Approach To Produce a Multidecker 4f Single-Molecule Magnet

2013 ◽  
Vol 135 (9) ◽  
pp. 3502-3510 ◽  
Author(s):  
Jennifer J. Le Roy ◽  
Matthew Jeletic ◽  
Serge I. Gorelsky ◽  
Ilia Korobkov ◽  
Liviu Ungur ◽  
...  
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Single Molecule Magnet ◽  
Block Approach

[Mn${{{{III}\hfill \atop 2\hfill}}}$(5-Rsaltmen)2NiII(pao)2(L)]2+: AnST=3 Building Block for a Single-Chain Magnet That Behaves as a Single-Molecule Magnet

2005 ◽  
Vol 11 (5) ◽  
pp. 1592-1602 ◽  
Author(s):  
Hitoshi Miyasaka ◽  
Tomohiro Nezu ◽  
Kunihisa Sugimoto ◽  
Ken-ichi Sugiura ◽  
Masahiro Yamashita ◽  
...  
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Single Chain ◽  
Single Molecule Magnet

Single-molecule magnet behavior in three cyano-bridged heterometallic FeIII–NiII clusters

2015 ◽  
Vol 44 (7) ◽  
pp. 3393-3398 ◽  
Author(s):  
Peng-Fei Zhuang ◽  
Yan-Juan Zhang ◽  
Hui Zheng ◽  
Cheng-Qi Jiao ◽  
Liang Zhao ◽  
...  
Keyword(s):  
Single Molecule ◽  
Building Block ◽  
Ancillary Ligands ◽  
Single Molecule Magnet ◽  
Divalent Nickel

By utilizing a tricyanometallate as the building block to react with divalent nickel salts in the presence of ancillary ligands, we successfully synthesized three cyano-bridged heterometallic FeIII–NiII complexes showing different single-molecule magnet behavior.

Discrete versus Chain Assembly: Hexacyanometallate Linkers and Macrocyclic {3d–4f} Single-Molecule Magnet Building Blocks

2019 ◽  
Vol 58 (9) ◽  
pp. 5543-5554 ◽  
Author(s):  
Sébastien Dhers ◽  
Humphrey L. C. Feltham ◽  
Mathieu Rouzières ◽  
Rodolphe Clérac ◽  
Sally Brooker
Keyword(s):  
Single Molecule ◽  
Building Blocks ◽  
Single Molecule Magnet
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