Use of dirhenium complexes as templates for the reductive coupling of carbon monoxide with alkynes through carbon-oxygen bond formation. Synthesis and characterization of 3-metallafuran complexes

1993 ◽  
Vol 115 (20) ◽  
pp. 9319-9320 ◽  
Author(s):  
Keng Yu Shih ◽  
Philip E. Fanwick ◽  
Richard A. Walton
Keyword(s):  
Carbon Monoxide ◽  
Bond Formation ◽  
Synthesis And Characterization ◽  
Reductive Coupling ◽  
Dirhenium Complexes ◽  
Oxygen Bond

Synthesis and characterization of polyketoximes derived from alkene-carbon monoxide copolymers

1996 ◽  
Vol 32 (11) ◽  
pp. 1285-1288 ◽  
Author(s):  
Shui-Yu Lu ◽  
R.Michael Paton ◽  
Michael J. Green ◽  
Andrew R. Lucy
Keyword(s):  
Carbon Monoxide ◽  
Synthesis And Characterization

Synthesis and Characterization of Trimetallic Complexes Containing M−Pd−M Arrays (M = Mo, W) and Their Relevance in Palladium-Catalyzed Metal−Carbon Bond Formation

2002 ◽  
Vol 21 (14) ◽  
pp. 3001-3008 ◽  
Author(s):  
Francesco Angelucci ◽  
Antonella Ricci ◽  
Claudio Lo Sterzo ◽  
Dante Masi ◽  
Claudio Bianchini ◽  
...  
Keyword(s):  
Bond Formation ◽  
Synthesis And Characterization ◽  
Carbon Bond ◽  
Palladium Catalyzed

Synthesis and characterization of N-glucosylated dithiadiazepine derivatives through carbon-sulfur bond formation

2015 ◽  
Vol 21 (5) ◽  
pp. 269-272 ◽  
Author(s):  
Snehal A. Chavan ◽  
Avinash G. Ulhe ◽  
Baliram N. Berad
Keyword(s):  
Bond Formation ◽  
Synthesis And Characterization ◽  
Mass Spectral ◽  
H Nmr ◽  
Chemical Structures ◽  
Elemental Analyses ◽  
New Compounds ◽  
Sulfur Bond ◽  
C Nmr

AbstractNew 4,7-bis(arylamino)-2-tetra-O-acetyl-β-d-glucopyranosylimino-1,3,5,6-dithiadiazepines were synthesized via reaction of N-tetra-O-acetyl-β-d-glucopyranosyl isocyanodichloride with 1,6-diaryl-2,5-dithio-bis-ureas without using any catalyst. Thus, the synthesis of 7-membered heterocycles containing two sulfur and two nitrogen atoms through carbon-sulfur bond formation was explored. The chemical structures of these new compounds were elucidated by IR, 1H NMR, 13C NMR, mass spectral, and elemental analyses.

Titanocene derivatives of purine and adenine. Synthesis and characterization of reaction products with (η5-C5H5)2Ti(CO)2, (η5-C5H5)2TiCl, and (η5-C5H5)2TiCl2

1986 ◽  
Vol 64 (4) ◽  
pp. 751-759 ◽  
Author(s):  
Daniel Cozak ◽  
Abdelhakim Mardhy ◽  
André Morneau
Keyword(s):  
Carbon Monoxide ◽  
Metal Complex ◽  
Elemental Analysis ◽  
Synthesis And Characterization ◽  
Reaction Products ◽  
First Order ◽  
H Nmr ◽  
New Compounds ◽  
Derivatives Of

The reaction of CpTi(CO)2 (1), Cp2TiCl (2), and Cp2TiCl2 (3) (Cp = η5-C5H5) with purine (PuH) and adenine (AdH) in organic solvents is described. The compound 1 reacts with both molecules in an oxidative fashion giving Cp2Ti(C5H3N4)(C5H4N4) (4) and (Cp2Ti)2(C5H3N5) (5) with concomitant liberation of molecular carbon monoxide and hydrogen (4:1) following a first order rate law in metal complex. The compound 2 forms an adduct compound Cp2TiCl(C5H4N4) (6) with PuH. Monosubstituted derivatives Cp2TiCl(C5H3N4) (7) and Cp2TiCl(C5H4N5) (8) are formed from the reaction of the deprotonated bases with 3. In addition to the usual elemental analysis, the characteristic ir, 1H nmr, epr, and ms results are given for the new compounds.

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