Synthesis and characterization of the paramagnetic [Ag13Fe8(CO)32]4- tetraanion: a cuboctahedral Ag13 cluster stabilized by Fe(CO)4 groups behaving as 4-electron donors

1992 ◽  
Vol 114 (14) ◽  
pp. 5708-5713 ◽  
Author(s):  
Vincenzo G. Albano ◽  
Loris Grossi ◽  
Giuliano Longoni ◽  
Magda Monari ◽  
Suzanne Mulley ◽  
...  
Keyword(s):  
Electron Donors ◽  
Synthesis And Characterization

Synthesis and Characterization of Novel Tetrathiafulvalene-Type Electron Donors Bearing Two Pyridine Groups

2006 ◽  
Vol 2006 (18) ◽  
pp. 4237-4241 ◽  
Author(s):  
Noura Benbellat ◽  
Yann Le Gal ◽  
Stéphane Golhen ◽  
Abdelkrim Gouasmia ◽  
Lahcène Ouahab ◽  
...  
Keyword(s):  
Electron Donors ◽  
Synthesis And Characterization

Facile Synthesis and Characterization of Naphthidines as a New Class of Highly Nonplanar Electron Donors Giving Robust Radical Cations

2006 ◽  
Vol 71 (4) ◽  
pp. 1351-1361 ◽  
Author(s):  
Christophe Desmarets ◽  
Benoît Champagne ◽  
Alain Walcarius ◽  
Christine Bellouard ◽  
Rafik Omar-Amrani ◽  
...  
Keyword(s):  
Radical Cations ◽  
Electron Donors ◽  
Synthesis And Characterization ◽  
Facile Synthesis ◽  
New Class

scholarly journals Φωτοκαταλυτική αναγωγή του νερού με χρήση διθειολενικών συμπλόκων

2016 ◽  
Author(s):  
Ευγενία Κουτσούρη
Keyword(s):  
Hydrogen Production ◽  
Visible Region ◽  
Electron Donors ◽  
Sodium Ascorbate ◽  
Synthesis And Characterization ◽  
Chemistry Department ◽  
Thermal Conductivity Detector ◽  
Ft Ir ◽  
Phd Thesis

This work was conducted within the PhD thesis in the field of Inorganic Chemistry andInorganic Technology, at the Inorganic Laboratory of the Chemistry Department of UoA. Itcovers literature photocatalytic systems for hydrogen production with homogeneousphotocatalysis, whereas experimental deals with the synthesis and characterization of complexesthat show strong absorptions in the visible region and could act as chromophores orphotocatalysts for hydrogen production. During this thesis complexes [Cu(4,4΄-dcbpy)2]Cl,where dcbpy=2,2'-bypiridine-4,4'-dicarboxylate and [Cu(5,5΄-dcbpy)2]Cl, where dcbpy=2,2'-bypiridine-5,5'-dicarboxylate, which can be used as proton reductive catalysts, have beensynthesized. Also, rhenium complexes have been prepared following the literature procedures:[Rebpy(CO)3Br], [Rebpy(CO)3Cl], [Rebpy(CO)3(MeCN)](PF6), [Rebpy(CO)3(NCS)](PF6),which can be used as chromophores. All these complexes were characterized byphysicochemical methods, FT-IR, UV-Vis, 1H-NMR, cyclic voltammetry (CV), andspectroscopy methods, emission. During this thesis the photocatalytic systems have been testedfor hydrogen production where the complexes [Rebpy(CO)3Br], [Rebpy(CO)3Cl],[Rebpy(CO)3(MeCN)](PF6), [Rebpy(CO)3(NCS)](PF6), [Ru(bpy)3]Cl2, [Ru(dcbpy)2Cl2],[Ru(dcbpy)2qdt] were used as photosensitizers (PS), the complexes [Ni{S2C2(Ph)2}2],[Ni{S2C2(Ph)2}2](NEt4), [Ni{S2C2(Ph)(Ph-OCH3-4)}2], [Ni{S2C2(Ph)(Ph-OCH3-4)}2](NEt4),[Ni{S2C2(Ph-OCH3-4)2}2], [Ni{S2C2(Ph-OCH3-4)2}2](NEt4), [Ni{S2C2(Ph)2}2C3],[Ni{S2C2(Ph)(Ph-OCH3-4)}2C3], [Ni{S2C2(Ph-OCH3-4)2}2C3], [Ni(bdt)2](TBA), [Ni(bdt)2C3],[Ni(S4C3)Fe(CO)Cp*](BF4), [W{S2C2(C6H5)2}3], [W{S2C2(C6H5)2}3](TBA), [Cu(4,4΄-dcbpy)2]Cl, and [Cu(5,5΄-dcbpy)2]Cl as proton reductive catalysts, and the speciestriethanolamine TEOA and ascorbic acid/sodium ascorbate as sacrificial electron donors. Σhesolvents used were DMF, DMF/ H2O, CH3CN/H2O, acetone, CH2Cl2, H2O. For the detection ofH2 a gas chromatographer with a thermal conductivity detector (TCD) was used.

Synthesis and Characterization of the Three Dicyclopentapyrenes

1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula
Keyword(s):  
Synthesis And Characterization
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