The Polarographic Determination of Relative Formation Constants of Metal Complexes of Ethylenediaminetetraacetic Acid

1953 ◽  
Vol 57 (9) ◽  
pp. 874-879 ◽  
Author(s):  
K. Bril ◽  
P. Krumholz
Keyword(s):  
Metal Complexes ◽  
Ethylenediaminetetraacetic Acid ◽  
Formation Constants ◽  
Polarographic Determination

Solubility and Complex-Ion Equilibria

2021 ◽  
pp. 313-324
Author(s):  
Christopher O. Oriakhi
Keyword(s):  
Metal Complexes ◽  
Solubility Product ◽  
Formation Constants ◽  
Aqueous Systems ◽  
Complex Ions ◽  
Ionic Compounds ◽  
Molar Solubility ◽  
Solubility Product Constant ◽  
Complex Ion

Solubility and Complex-Ion Equilibria broadens the previous chapter’s coverage of equilibria to include aqueous systems containing two or more solutes of slightly soluble ionic compounds and the formation of metal complexes in solution. Solubility equilibria which allow quantitative predictions of how much of a compound will dissolve under given conditions are covered. The meaning of the solubility product constant (K sp) and how to calculate it from molar solubility values is presented. Also discussed is determination of molar solubility from K sp. Calculations demonstrate how to predict the formation of a precipitate by comparing the ion product or solubility quotient (Q) with K sp. Formation constants of complex ions and calculations involving complex ion equilibria are explained.

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