The γ Radiolysis of Liquid 2-Propanol. II.1aThe Reaction of Solvated Electrons with Mono- and Disubstituted Benzenes

1966 ◽  
Vol 70 (9) ◽  
pp. 2872-2875 ◽  
Author(s):  
Warren V. Sherman
Keyword(s):  
Solvated Electrons

Photoredox Reactions of Iodo Iron(III) Complexes Containing Tetradentate Ligands

2001 ◽  
Vol 66 (1) ◽  
pp. 109-118 ◽  
Author(s):  
Jozef Šima ◽  
Dáša Lauková ◽  
Vlasta Brezová
Keyword(s):  
Schiff Bases ◽  
Spin Trapping ◽  
Molar Ratio ◽  
Oh Radicals ◽  
Solvated Electrons ◽  
Open Chain ◽  
Tetradentate Ligands ◽  
Visible Irradiation ◽  
Epr Spin Trapping ◽  
Spin Trapping Technique

Photoredox reactions occurring in irradiated methanolic solutions of trans-[FeIII(R,R'-salen)(CH3OH)I], where R,R'-salen2- are N,N'-ethylenebis(R,R'-salicylideneiminato), tetradentate open-chain N2O2-Schiff bases with R,R' = H, 5-Cl, 5-Br, 3,5-di-Br, 3,5-di-(CH3), 3-OCH3, 5-OCH3, have been investigated and their mechanism proposed. The complexes are redox-stable in the dark. Ultraviolet and/or visible irradiation of methanolic solution of the complexes induces photoreduction of Fe(III) to Fe(II). Depending on the composition of the irradiated solutions, •CH2OH radicals or solvated electrons were identified by the EPR spin trapping technique. The final product of the photooxidation coupled with the photoreduction of Fe(III) is formaldehyde and the molar ratio of Fe(II) and CH2O is close to 2 : 1. The efficiency of the photoredox process is strongly wavelength-dependent and influenced by the peripheral groups R,R' of the tetradentate ligands.

Relaxation dynamics following transition of solvated electrons

1989 ◽  
Vol 90 (8) ◽  
pp. 4413-4422 ◽  
Author(s):  
R. B. Barnett ◽  
Uzi Landman ◽  
Abraham Nitzan
Keyword(s):  
Relaxation Dynamics ◽  
Solvated Electrons

Wavelength Dependence of UV Photoemission from Solvated Electrons in Bulk Water, Methanol, and Ethanol

2016 ◽  
Vol 120 (8) ◽  
pp. 1153-1159 ◽  
Author(s):  
Yo-ichi Yamamoto ◽  
Shutaro Karashima ◽  
Shunsuke Adachi ◽  
Toshinori Suzuki
Keyword(s):  
Wavelength Dependence ◽  
Bulk Water ◽  
Solvated Electrons

Article

1998 ◽  
Vol 76 (4) ◽  
pp. 411-413
Author(s):  
Yixing Zhao ◽  
Gordon R Freeman
Keyword(s):  
Absorption Spectrum ◽  
Optical Absorption ◽  
Temperature Dependence ◽  
Optical Absorption Spectrum ◽  
Infrared Light ◽  
Solvated Electron ◽  
Solvated Electrons ◽  
Tert Butanol ◽  
Solvent Dependence ◽  
Increasing Temperature

The energy and asymmetry of the optical absorption spectrum of solvated electrons, es- , change in a nonlinear fashion on changing the solvent through the series HOH, CH3OH, CH3CH3OH, (CH3)2CHOH, (CH3)3COH. The ultimate, quantum-statistical mechanical, interpretation of solvated electron spectra is needed to describe the solvent dependence. The previously reported optical spectrum of es- in tert-butanol was somewhat inaccurate, due to a small amount of water in the alcohol and to limitations of the infrared light detector. The present note records the remeasured spectrum and its temperature dependence. The value of the energy at the absorption maximum (EAmax) is 155 zJ (0.97 eV) at 299 K and 112 zJ (0.70 eV) at 338 K; the corresponding values of G epsilon max (10-22 m2 aJ-1) are 1.06 and 0.74. These unusually large changes are attributed to the abnormally rapid decrease of dielectric permittivity of tert-butanol with increasing temperature. The band asymmetry at 299 K is Wb/Wr = 1.8.Key words: optical absorption spectrum, solvated electron, solvent effects, tert-butanol, temperature dependence.

Nonlinear Terahertz Response of Solvated Electrons in Liquid Water

2020 ◽  
Author(s):  
A. Ghalgaoui ◽  
B. P. Fingerhut ◽  
K. Reimann ◽  
M. Woerner ◽  
T. Elsaesser
Keyword(s):  
Liquid Water ◽  
Solvated Electrons

Effect of voltage polarity and supply frequency on properties of plasma contacting liquid electrode and gold nanoparticle synthesis

2021 ◽  
Author(s):  
Phuoc Van Thai ◽  
Nobuo Saito ◽  
Tsubasa Nakamura ◽  
Kazumasa Takahashi ◽  
Toru Sasaki ◽  
...  
Keyword(s):  
Gold Nanoparticle ◽  
Charged Particles ◽  
Nanoparticle Synthesis ◽  
Chemical Properties ◽  
Bulk Liquid ◽  
Solvated Electrons ◽  
Plasma Properties ◽  
Voltage Polarity ◽  
Specific Species ◽  
Gold Nanoparticle Synthesis

Abstract Plasma contacting with liquid provides many charged particles and reactive species into the liquid. The difficulty in controlling or selecting each specific species has significantly limited its applications in industry. Here, we present a study on using voltage polarity to regulate the type of charged particles absorbing from plasma into liquid. Detailed understanding of the processes at the plasma-liquid interface, electrolysis due to switching in voltage polarity was investigated via a visual pH observation, measuring the concentration of H2O2 and solvated electrons. The results indicated that changing in voltage polarity strongly affects the plasma properties, chemical properties, and electrolysis process in liquid, and further in the types of reducing species for gold nanoparticle synthesis. The results also showed using a suitable frequency could improve the efficiency of absorption of H2O2from plasma into the bulk liquid and the yield in the production of gold nanoparticles. The results provide a way to select desired species from plasma into the liquid for a distinct purpose and accompanying other properties in the system of plasma contacting with liquid.

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