THE ABSOLUTE ADSORPTION ISOTHERMS OF VAPORS OF NITROGEN, BENZENE AND n-HEXANE, AND THE HEATS OF ADSORPTION OF BENZENE AND n-HEXANE ON GRAPHITIZED CARBON BLACKS. I. GRAPHITIZED THERMAL BLACKS

1961 ◽  
Vol 65 (4) ◽  
pp. 601-607 ◽  
Author(s):  
A. A. Isirikyan ◽  
A. V. Kiselev
Keyword(s):  
Adsorption Isotherms ◽  
Heats Of Adsorption ◽  
Carbon Blacks ◽  
Graphitized Carbon ◽  
Absolute Adsorption ◽  
The Absolute

ISOTHERMS OF BROMINE ON GRAPHITE

1959 ◽  
Vol 37 (5) ◽  
pp. 899-904 ◽  
Author(s):  
J. G. Hooley
Keyword(s):  
Adsorption Isotherms ◽  
Kcal Mole ◽  
Natural Graphite ◽  
Heats Of Adsorption ◽  
Carbon Blacks ◽  
Surface Areas

The isotherms of bromine on eight carbon blacks and on natural graphite have been related to the known structures of these materials. The surface areas can be calculated from the adsorption isotherms and the size of the graphite crystals can be estimated from the extent of hysteresis on desorption. The isosteric heats of adsorption on the surface and between the layers are each 11 kcal mole−1. The formation of residue compounds displaces the isotherms equally at all pressures.

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