ADSORPTION ISOTHERMS OF NITROGEN, BENZENE AND n-HEXANE AND THE HEATS OF ADSORPTION OF BENZENE AND n-HEXANE ON GRAPHITIZED CARBON BLACKS. III. THE THERMODYNAMIC CHARACTERISTICS OF ADSORPTION EQUILIBRIA

1962 ◽  
Vol 66 (2) ◽  
pp. 210-215 ◽  
Author(s):  
A. A. Isirikyan ◽  
A. V. Kiselev
Keyword(s):  
Adsorption Isotherms ◽  
Thermodynamic Characteristics ◽  
Heats Of Adsorption ◽  
Carbon Blacks ◽  
Graphitized Carbon ◽  
Adsorption Equilibria ◽  
Thermodynamic Characteristics Of Adsorption

ISOTHERMS OF BROMINE ON GRAPHITE

1959 ◽  
Vol 37 (5) ◽  
pp. 899-904 ◽  
Author(s):  
J. G. Hooley
Keyword(s):  
Adsorption Isotherms ◽  
Kcal Mole ◽  
Natural Graphite ◽  
Heats Of Adsorption ◽  
Carbon Blacks ◽  
Surface Areas

The isotherms of bromine on eight carbon blacks and on natural graphite have been related to the known structures of these materials. The surface areas can be calculated from the adsorption isotherms and the size of the graphite crystals can be estimated from the extent of hysteresis on desorption. The isosteric heats of adsorption on the surface and between the layers are each 11 kcal mole−1. The formation of residue compounds displaces the isotherms equally at all pressures.

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