ACID—BASE EQUILIBRIA IN CONCENTRATED SALT SOLUTIONS. I. POTENTIOMETRIC MEASUREMENTS, INDICATOR MEASUREMENTS, AND UNCHARGED BASES IN DILUTE ACID SOLUTIONS1

1962 ◽  
Vol 66 (12) ◽  
pp. 2687-2691 ◽  
Author(s):  
Donald Rosenthal ◽  
James S. Dwyer
Keyword(s):  
Dilute Acid ◽  
Salt Solutions ◽  
Acid Base ◽  
Potentiometric Measurements

Acid-Base Equilibria in Concentrated Salt Solutions. IV. Some Bases of Various Charge Types in Dilute Acid Solutions1,2

1965 ◽  
Vol 69 (5) ◽  
pp. 1588-1595 ◽  
Author(s):  
Donald Rosenthal ◽  
Ignatius T. Oiwa ◽  
Augustus D. Saxton ◽  
Louis R. Lieto
Keyword(s):  
Dilute Acid ◽  
Salt Solutions ◽  
Acid Base

Solubility of simple aluminium compounds expected in soils. II. Hydrolysis and conductance of Al3+

Soil Research ◽  
1963 ◽  
Vol 1 (1) ◽  
pp. 36 ◽  
Author(s):  
M Raupach
Keyword(s):  
Aluminium Hydroxide ◽  
Aluminium Chloride ◽  
Salt Solutions ◽  
Chloride Solutions ◽  
Aluminium Salt ◽  
Potentiometric Measurements ◽  
Limiting Equivalent Conductances

The results of conductimetric measurements on dilute aluminium chloride solutions at 25� were found to be best fitted by the limiting equivalent conductances A01/3Al3 + = A01/2AlOH2+ = 58.2 with the parameter for ionic diameter 6.0A and by *K1 = log [(AlOH2+)(H+)/(Al3+)] = - 5.05 when it was assumed that AlOH2+ and H+ concentrations produced by hydrolysis were equal in the measured solutions. Potentiometric measurements and calculations from solubility work gave *K1 = -5.00 and -4.97 respectively. After small changes, e.g. by aging, dilute aluminium salt solutions conform to the solubility expression for aluminium hydroxide, log [(AlOH2+) (OH-)2] = -23.31.

Unified Molecular Picture of the Surfaces of Aqueous Acid, Base, and Salt Solutions

2005 ◽  
Vol 109 (16) ◽  
pp. 7617-7623 ◽  
Author(s):  
Martin Mucha ◽  
Tomaso Frigato ◽  
Lori M. Levering ◽  
Heather C. Allen ◽  
Douglas J. Tobias ◽  
...  
Keyword(s):  
Salt Solutions ◽  
Acid Base ◽  
Aqueous Acid ◽  
Molecular Picture
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