Reduction of cobalt(III) complexes by monovalent zinc, cadmium, and nickel ions in aqueous solutions

1969 ◽  
Vol 73 (4) ◽  
pp. 1091-1095 ◽  
Author(s):  
Dan Meyerstein ◽  
W. A. Mulac
1964 ◽  
Vol 46 (4) ◽  
pp. 643-652 ◽  
Author(s):  
M. Anbar ◽  
M. Inbar

ABSTRACT Ferric, cupric, mercuric, zinc, cadmium and nickel ions at the dose level of 0.1 millimole per kg body weight were found to decrease the uptake of iodine in the thyroid gland. Manganous ions exhibited a similar effect when the dose was doubled. A parallel decrease in the BF4− uptake could be demonstrated; this suggests an interference at the stage of iodide accumulation. Cobaltous, cobaltic, magnesium, beryllium and zirconium ions were shown to have no effect on iodine uptake at the same dose level. The mechanism of the effect is discussed.


2017 ◽  
Author(s):  
A. Al-Gheethi ◽  
A. N. Efaq ◽  
R. M. Mohamed ◽  
M. Abdel-Monem ◽  
M. Amir Hashim

2017 ◽  
Vol 32 (2) ◽  
pp. 276-284 ◽  
Author(s):  
Katerina Atkovska Burevska ◽  
Hamdije Memedi ◽  
Kiril Lisichkov ◽  
Stefan Kuvendziev ◽  
Mirko Marinkovski ◽  
...  

Carbon ◽  
2002 ◽  
Vol 40 (7) ◽  
pp. 1109-1115 ◽  
Author(s):  
B.M Babić ◽  
S.K Milonjić ◽  
M.J Polovina ◽  
S Čupić ◽  
B.V Kaludjerović

Author(s):  
Oksana MYAKUSH ◽  
◽  
Leonid SYSA ◽  

The article is a continuation of a series of scientific works of the authors on the study of the influence of microwave irradiation on the sorption parameters of natural sorbents in the processes of purification of natural and wastewater. Using the atomic absorption method, the sorption ability of the natural sorbent clinoptilolite (zeolite type of structure) to remove Copper, Zinc and Nickel ions from aqueous solutions was studied. It was found that different variants of microwave activation of this mineral (series «Nat», «Stim» and «DIR») lead to a significant increase in the sorption capacity of clinoptilolite by ions of these heavy metals. It is shown that in comparison with similar activation schemes of another natural sorbent of bentonite (clay material), the improvement of sorption parameters of clinoptilolite with respect to heavy metals is not as significant as in the case of bentonite. It is confirmed that in almost all solutions the deposition of heavy metals on clinoptilolite occurs according to the Langmuir or Langmuir-Freundlich model. A similar situation was observed in previous works of the authors on the deposition of heavy metals on bentonite. Using scanning electron microscopy, energy dispersion spectroscopy and X-ray phase analysis, it was found that the deposition of heavy metals on both bentonite and clinoptilolite occurs not only in the form of monolayers of hydrated ions in sorbent micropores (classical model), but also in the form of individual compounds. metals. It has been suggested that the action of microwaves on these sorbents in aqueous solutions improves the structure of their micropores and affects the surface charge, so some parts of the adsorbent become active centers of crystallization of new phases - heavy metal compounds. During adsorption of heavy metal by natural bentonite or clinoptilolite, low-energy adsorption centers predominate, whereas in the case of microwave-irradiated samples of these sorbents, the experimental data correspond to a symmetric quasi-Gaussian distribution of adsorption energy where low- and high-energy regions are present. This fact indicates that electromagnetic treatment stimulates the formation of new adsorption centers.


2017 ◽  
Vol 68 (1) ◽  
pp. 1-5
Author(s):  
Rodica Elena Patescu ◽  
Claudia Maria Simonescu ◽  
Cristian Onose ◽  
Teodor Laurentiu Busuioc ◽  
Daiana Elena Pasarica ◽  
...  

This research study deals with lead and nickel simultaneous removal from aqueous solutions by the use of chitosan coated cobalt ferrite as adsorbent. Batch removal tests were performed in order to establish the main parameters that influence the sorption capacity, removal efficiency and the selectivity of this adsorbent. The values of sorption capacity for lead and nickel experimentally determined are: 56.23 mg/g and respectively 45.11 mg/g. Langmuir and Freundlich adsorption isotherms were used to interpret the sorption experimental data. The kinetic data were explored by pseudo-first order, pseudo-second order and intraparticle diffusion kinetic models. The experimental data were well fitted with the pseudo-second order model for both heavy metals. The main conclusion that can be drawn from this research is that this material can be successfully used for the removal of lead and nickel from binary aqueous solutions and wastewater.


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