Vacuum-ultraviolet photolysis of polydimethylsiloxane. Gas yields and energy transfer

1969 ◽  
Vol 73 (4) ◽  
pp. 823-828 ◽  
Author(s):  
Seymour Siegel ◽  
Thomas Stewart
1972 ◽  
Vol 50 (10) ◽  
pp. 1443-1447 ◽  
Author(s):  
S. C. Chan ◽  
Y. Inel ◽  
E. Tschuikow-Roux

The photolysis of C2H5F at 147 nm was studied at room temperature. The principal products include C2H3F, C2H2, C2H4, CH4, and C2H6. The principal primary photochemical reactions involve the molecular elimination of HF and H2, and, to a lesser extent, C—F and C—C bond fission. The effect of reactant and added inert gas pressure on the product yields has been investigated and it was found that the stabilization/decomposition ratio, C2H4/C2H2, displays opposite pressure dependence with ethyl fluoride and argon. This result is interpreted in terms of the higher energy transfer efficiency of the C2H5F molecule.


1981 ◽  
Vol 55 (1-2) ◽  
pp. 9-15 ◽  
Author(s):  
A. Jówko ◽  
S. U. Pavlova ◽  
H. Baj ◽  
B. G. Dzantiev ◽  
M. Foryś

1994 ◽  
Vol 79-80 ◽  
pp. 476-480 ◽  
Author(s):  
P. Fons ◽  
T. Motooka ◽  
K. Awazu ◽  
H. Onuki

1969 ◽  
Vol 50 (1) ◽  
pp. 309-311 ◽  
Author(s):  
R. A. Young ◽  
G. Black ◽  
T. G. Slanger

Author(s):  
Bongolwethu P. Mabusela ◽  
Zinash A. Belay ◽  
Buntu Godongwana ◽  
Namrata Pathak ◽  
Pramod V. Mahajan ◽  
...  

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