Radiative processes of the solvated electron in polar fluids

1973 ◽  
Vol 77 (8) ◽  
pp. 1040-1050 ◽  
Author(s):  
Neil R. Kestner ◽  
Joshua Jortner
Keyword(s):  
Solvated Electron ◽  
Polar Fluids ◽  
Radiative Processes

scholarly journals Impacts of Ozone Changes in the Tropopause Layer on Stratospheric Water Vapor

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 291
Author(s):  
Jinpeng Lu ◽  
Fei Xie ◽  
Hongying Tian ◽  
Jiali Luo
Keyword(s):  
Water Vapor ◽  
Ozone Depletion ◽  
Climate Model ◽  
Global Climate ◽  
Stratospheric Water Vapor ◽  
Radiative Processes ◽  
Low Latitudes ◽  
Cold Point ◽  
The Impact ◽  
Tropopause Temperature

Stratospheric water vapor (SWV) changes play an important role in regulating global climate change, and its variations are controlled by tropopause temperature. This study estimates the impacts of tropopause layer ozone changes on tropopause temperature by radiative process and further influences on lower stratospheric water vapor (LSWV) using the Whole Atmosphere Community Climate Model (WACCM4). It is found that a 10% depletion in global (mid-low and polar latitudes) tropopause layer ozone causes a significant cooling of the tropical cold-point tropopause with a maximum cooling of 0.3 K, and a corresponding reduction in LSWV with a maximum value of 0.06 ppmv. The depletion of tropopause layer ozone at mid-low latitudes results in cooling of the tropical cold-point tropopause by radiative processes and a corresponding LSWV reduction. However, the effect of polar tropopause layer ozone depletion on tropical cold-point tropopause temperature and LSWV is opposite to and weaker than the effect of tropopause layer ozone depletion at mid-low latitudes. Finally, the joint effect of tropopause layer ozone depletion (at mid-low and polar latitudes) causes a negative cold-point tropopause temperature and a decreased tropical LSWV. Conversely, the impact of a 10% increase in global tropopause layer ozone on LSWV is exactly the opposite of the impact of ozone depletion. After 2000, tropopause layer ozone decreased at mid-low latitudes and increased at high latitudes. These tropopause layer ozone changes at different latitudes cause joint cooling in the tropical cold-point tropopause and a reduction in LSWV. Clarifying the impacts of tropopause layer ozone changes on LSWV clearly is important for understanding and predicting SWV changes in the context of future global ozone recovery.

Electric field impact on solvated electron reactions: Trapping of randomly walking electron

1999 ◽  
Vol 111 (13) ◽  
pp. 6016-6025 ◽  
Author(s):  
S. G. Fedorenko ◽  
E. B. Krissinel ◽  
A. I. Burshtein
Keyword(s):  
Electric Field ◽  
Solvated Electron

Radiative processes in glasses in glasses in the system Ba(Po3)2-MgF2-LiF

1984 ◽  
Vol 41 (5) ◽  
pp. 1292-1294
Author(s):  
T. V. Bocharova ◽  
G. O. Karapetyan ◽  
V. D. Khalilev
Keyword(s):  
Radiative Processes

Cells Containing Solvated Electron Lithium Negative Electrodes

1989 ◽  
Vol 136 (12) ◽  
pp. 3559-3565 ◽  
Author(s):  
Francisco A. Uribe ◽  
Krystyna W. Semkow ◽  
Anthony F. Sammells
Keyword(s):  
Solvated Electron ◽  
Negative Electrodes

Theoretical studies of excitation dynamics in a peridinin-chlorophyll-protein coupled to a metallic nanoparticle

Open Physics ◽  
2011 ◽  
Vol 9 (2) ◽  
Author(s):  
Mikolaj Schmidt ◽  
Sebastian Mackowski
Keyword(s):  
Energy Transfer ◽  
Metallic Surface ◽  
Energy Transfer Rate ◽  
Metallic Nanoparticle ◽  
Light Harvesting Complex ◽  
Radiative Processes ◽  
Förster Energy Transfer ◽  
Chlorophyll Protein ◽  
Induced Changes ◽  
Excitation Dynamics

AbstractIn this work we study the influence of plasmon excitations on the excitation dynamics within a protein complex embedding two chlorophyll molecules coupled to a gold nanosphere. Small separation between the chlorophylls and metallic nanoparticle allows us to simplify the calculations of the Förster energy transfer rate and non-radiative processes by replacing a spherical nanoparticle with a metallic surface. Our results show modifications of all relevant processes and the energy transfer pathways within the system as well as the radiative processes. Plasmon induced changes result in strong qualitative effects of the fluorescence of the studied light-harvesting complex.

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