Estimating microsecond rotational correlation times from lifetime broadening of nitroxide electron spin resonance spectra near the rigid limit

Ronald Paul Mason; Jack H. Freed

doi:10.1021/j100606a015

Estimating microsecond rotational correlation times from lifetime broadening of nitroxide electron spin resonance spectra near the rigid limit

The Journal of Physical Chemistry ◽

10.1021/j100606a015 ◽

1974 ◽

Vol 78 (13) ◽

pp. 1321-1323 ◽

Cited By ~ 88

Author(s):

Ronald Paul Mason ◽

Jack H. Freed

Keyword(s):

Electron Spin Resonance ◽

Electron Spin ◽

Correlation Times ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Rotational Correlation

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Electron spin resonance studies of spin-labelled polymers. Part 7.—Dependence of rotational correlation times on solvent properties and polymer concentration

Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics ◽

10.1039/f29747001202 ◽

1974 ◽

Vol 70 (0) ◽

pp. 1202-1210 ◽

Cited By ~ 26

Author(s):

Anthony T. Bullock ◽

G. Gordon Cameron ◽

Peter M. Smith

Keyword(s):

Electron Spin Resonance ◽

Electron Spin ◽

Polymer Concentration ◽

Correlation Times ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Solvent Properties ◽

Rotational Correlation

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Estimating slow-motional rotational correlation times for nitroxides by electron spin resonance

The Journal of Physical Chemistry ◽

10.1021/j100657a013 ◽

1972 ◽

Vol 76 (13) ◽

pp. 1858-1860 ◽

Cited By ~ 197

Author(s):

S. A. Goldman ◽

G. V. Bruno ◽

J. H. Freed

Keyword(s):

Electron Spin Resonance ◽

Electron Spin ◽

Correlation Times ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Rotational Correlation

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Electron spin resonance studies of spin-labeled polymers. III. Molecular weight dependence of segmental rotational correlation times of polystyrene in dilute solution

The Journal of Physical Chemistry ◽

10.1021/j100632a008 ◽

1973 ◽

Vol 77 (13) ◽

pp. 1635-1639 ◽

Cited By ~ 43

Author(s):

A. T. Bullock ◽

G. G. Cameron ◽

P. M. Smith

Keyword(s):

Molecular Weight ◽

Electron Spin Resonance ◽

Electron Spin ◽

Dilute Solution ◽

Correlation Times ◽

Molecular Weight Dependence ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Rotational Correlation

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Scaling Analysis and Distribution of the Rotational Correlation Times of a Tracer in Rubbery and Glassy Poly(vinyl acetate): An Electron Spin Resonance Investigation

Macromolecules ◽

10.1021/ma981178x ◽

1999 ◽

Vol 32 (6) ◽

pp. 1876-1882 ◽

Cited By ~ 45

Author(s):

M. Faetti ◽

M. Giordano ◽

D. Leporini ◽

L. Pardi

Keyword(s):

Electron Spin Resonance ◽

Vinyl Acetate ◽

Electron Spin ◽

Scaling Analysis ◽

Correlation Times ◽

Resonance Investigation ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Electron Spin Resonance Investigation ◽

Rotational Correlation

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Stable free radicals. IX. Use of halogen nuclear quadrupole coupling in electron spin resonance spectra of imino nitroxides for determination of solvent effects on rotational correlation times

Journal of the American Chemical Society ◽

10.1021/ja00727a037 ◽

1970 ◽

Vol 92 (24) ◽

pp. 7210-7212 ◽

Cited By ~ 11

Author(s):

Edwin F. Ullman ◽

Ludwig. Call

Keyword(s):

Free Radicals ◽

Electron Spin Resonance ◽

Electron Spin ◽

Solvent Effects ◽

Quadrupole Coupling ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Nuclear Quadrupole ◽

Stable Free Radicals

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The effect of osmotic pressure of aqueous PEG solutions on red blood cells

Bioscience Reports ◽

10.1007/bf01117001 ◽

1985 ◽

Vol 5 (8) ◽

pp. 689-696 ◽

Cited By ~ 11

Author(s):

Andreas Herrmann ◽

Klaus Arnold ◽

Lothar Pratsch

Keyword(s):

Electron Spin Resonance ◽

Polyethylene Glycol ◽

Red Blood Cells ◽

Osmotic Pressure ◽

Electron Spin ◽

Blood Cells ◽

Spin Resonance ◽

Rotational Correlation Times ◽

Drastic Increase ◽

Label Molecule

A drastic increase of the intracellular microviscosity of red blood cells in the presence of polyethylene glycol (PEG) was established by electron spin resonance using the small spin label molecule 2,2,6,6-tetramethylpiperidine-N-oxyl-4-one (TEMPONE). The effective osmotic pressure of PEG solutions stressing the cells was estimated by comparison with those cytoplasmic rotational correlation times of TEMPONE measured in NaCl or sucrose containing media of known osmotic pressure.

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