Rate constant for carbon monoxide + molecular oxygen = carbon dioxide + atomic oxygen from 1500 to 2500.deg. K. Reevaluation of induction times in the shock-initiated combustion of hydrogen-oxygen-carbon monoxide-argon mixtures

1974 ◽  
Vol 78 (5) ◽  
pp. 497-500 ◽  
Author(s):  
W. T. Rawlins ◽  
W. C. Gardiner
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Molecular Oxygen ◽  
Rate Constant ◽  
Atomic Oxygen ◽  
Induction Times ◽  
Combustion Of Hydrogen

The oxidation of Carbon with Atomic Oxygen

1959 ◽  
Vol 12 (2) ◽  
pp. 114 ◽  
Author(s):  
JD Blackwood ◽  
FK McTaggart
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Radio Frequency ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Graphitic Carbon ◽  
Carbon Surface ◽  
Direct Oxidation ◽  
Radio Frequency Field ◽  
Frequency Field

Atomic oxygen, produced by dissociation of molecular oxygen in a radio frequency field, will react with amorphous or graphitic carbon at room temperatures and both carbon monoxide and carbon dioxide appear in the product gases. Carbon monoxide appears to be the primary product of oxidation of carbon, the carbon dioxide being produced by direct combination of carbon monoxide with oxygen which takes place mainly at the carbon surface. Atomic oxygen will also react with carbon dioxide to produce carbon monoxide and molecular oxygen but the quantity of carbon monoxide produced by this reaction is small compared to that produced by direct oxidation of the carbon.

Low-Fluence Laser Induced Fragmentation and Desorption of 3,4,9,10-Perylenetetracarboxylic Dianhydride (PTCDA) Thin Film

2013 ◽  
Vol 543 ◽  
pp. 30-34 ◽  
Author(s):  
Aljona Ramonova ◽  
Tengiz Butkhuzi ◽  
Viktorija Abaeva ◽  
I.V. Tvauri ◽  
Soslan Khubezhov ◽  
...  
Keyword(s):  
Thin Film ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Kinetic Energy ◽  
Atomic Oxygen ◽  
Laser Light ◽  
Pulsed Laser ◽  
Molecular Fragmentation ◽  
Irradiation Pulse ◽  
Main Effect

Laser-induced fragmentation and desorption of fragments of PTCDA films vacuum-deposited on GaAs (100) substrate has been studied by time-of-flight (TOF) mass spectroscopy. The main effect caused by pulsed laser light irradiation (pulse duration: 10 ns, photon energy: 2.34 eV and laser fluence ranging from 0.5 to 7 mJ/cm2) is PTCDA molecular fragmentation and desorption of the fragments formed, whereas no desorption of intact PTCDA molecule was detected. Fragments formed are perylene core C20H8, its half C10H4, carbon dioxide, carbon monoxide and atomic oxygen. All desorbing fragments have essentially different kinetic energy. The mechanism of photoinduced molecular fragmentation and desorption is discussed.

scholarly journals Mariner 6: Ultraviolet spectrum of Mars upper atmosphere

1971 ◽  
Vol 40 ◽  
pp. 253-256 ◽  
Author(s):  
C. A. Barth ◽  
W. G. Fastie ◽  
C. W. Hord ◽  
J. B. Pearce ◽  
K. K. Kelly ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Spectral Region ◽  
Atomic Hydrogen ◽  
Atomic Oxygen ◽  
Ultraviolet Spectrum ◽  
Upper Atmosphere

Emission features from ionized carbon dioxide and carbon monoxide were measured in the 1900- to 4300-Å spectral region. The Lyman-α 1216-Å line of atomic hydrogen and the 1304-, 1356-, and 2972-Å lines of atomic oxygen were observed.

scholarly journals Atomic Oxygen Treatment Technique for Removal of Smoke Damage From Paintings

1996 ◽  
Vol 462 ◽  
Author(s):  
S.K. Rutledge ◽  
B.A. Banks
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Optical Microscopy ◽  
Atomic Oxygen ◽  
Reflectance Spectroscopy ◽  
Smoke Exposure ◽  
Treatment Technique ◽  
Oil Painting ◽  
Oxygen Treatment

ABSTRACTSoot deposits that can accumulate on surfaces of a painting during a fire can be difficult to clean from some types of paintings without damaging the underlying paint layers. A non-contact technique has been developed which can remove the soot by allowing a gas containing atomic oxygen to flow over the surface and chemically react with the soot to form carbon monoxide and carbon dioxide. The reaction is limited to the surface, so the underlying paint is not touched. The process can be controlled so that the cleaning can be stopped once the paint surface is reached. This paper describes the smoke exposure and cleaning of untreated canvas, acrylic gesso, and sections of an oil painting using this technique. The samples were characterized by optical microscopy and reflectance spectroscopy.

scholarly journals Photodissociation of Carbon Dioxide in the Mars Upper Atmosphere

1974 ◽  
Vol 29 (2) ◽  
pp. 185-188
Author(s):  
Charles A. Barth
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Atomic Oxygen ◽  
Emission Rate ◽  
Upper Atmosphere ◽  
Emission Rates ◽  
Laboratory Measurements

Photodissociation of carbon dioxide produces O (1S) atoms and CO (a3Π) molecules in the Mars upper atmosphere. Calculations of the emission rate of the atomic oxygen 2972 Å line and the carbon monoxide Cameron bands produced by the photodissociation mechanism are factors of 3 and 10, respectively, smaller than the emission rates observed by Mariner ultraviolet spectrometers. Laboratory measurements are needed to understand the discrepancies.

scholarly journals Pyrolysis of phenylmercaptoacetic acid

1968 ◽  
Vol 46 (2) ◽  
pp. 191-197 ◽  
Author(s):  
A. T. C. H. Tan ◽  
A. H. Sehon
Keyword(s):  
Carbon Dioxide ◽  
Activation Energy ◽  
Carbon Monoxide ◽  
Acetic Acid ◽  
Rate Constant ◽  
Order Reaction ◽  
First Order Reaction ◽  
Kcal Mole ◽  
Dissociation Process ◽  
First Order

The pyrolysis of phenylmercaptoacetic acid was investigated by the toluene-carrier technique over the temperature range 760–835 °K. The main products of the decomposition were phenyl mercaptan, carbon dioxide, acetic acid, phenyl methyl sulfide, carbon monoxide, and dibenzyl.The overall decomposition was a first-order reaction with respect to phenylmercaptoacetic acid and could be represented by the two parallel steps:[Formula: see text]Reaction [1] was shown to be a homogeneous first-order dissociation process, and its rate constant was represented by the expression[Formula: see text]The activation energy of this reaction, i.e. 58 kcal/mole, was identified with D(C6H5S—CH2COOH).

THE THERMAL CIS–TRANS ISOMERIZATION AND DECOMPOSITION OF METHYL CROTONATE

1963 ◽  
Vol 41 (10) ◽  
pp. 2492-2499 ◽  
Author(s):  
James N. Butler ◽  
Gerald J. Small
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Free Radical ◽  
Gas Phase ◽  
Rate Constant ◽  
Radical Reactions ◽  
Side Reactions ◽  
Free Radical Reactions ◽  
Trans Isomerization

Methyl crotonate undergoes a homogeneous, unimolecular cis–trans isomerization in the gas phase at temperatures from 400 °C to 560 °C. The rate constant for the cis → trans reaction was found to be [Formula: see text]independent of pressure in the range from 0.1 mm to 10 mm. The equilibrium trans/cis ratio is approximately 4.5, independent of temperature, from 200 °C to 500 °C. Simultaneous free-radical reactions also occur, the most important of which are the isomerization to methyl vinylacetate, and the decomposition to give carbon dioxide and the various butene isomers. Side reactions gave carbon monoxide, methane, propylene, numerous other hydrocarbons, and various ethers.

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