Excimer-laser-induced photochemistry of organometallic compounds monitored by dye laser mass spectroscopy: dimethyl ditelluride (CH3TeTeCH3)

1986 ◽  
Vol 90 (19) ◽  
pp. 4568-4573 ◽  
Author(s):  
R. Larciprete ◽  
M. Stuke
1988 ◽  
Vol 129 ◽  
Author(s):  
Th. Beuermann ◽  
M. Stuke

ABSTRACTWe use tunable UV laser light in the region 200-320 nm, produced by frequency doubling the output of a dye laser for the decomposition of organometallic compounds. This method has been applied to TMA, trimethylaluminum AI(CH3)3. Only theTMA monomer absorbs UV light for λ>220nm. TMA decomposes by one-photon absorption mainly into two channels: aluminum plus organic fragments and aluminummonomethyl plus organic fragments. The ratio [A1]/[AICH3] is wavelength dependent. Finally, we present a mechanism to explain the photolysis of trimethyl compounds of group III elements (Al,Ga,In).


1985 ◽  
Vol 24 (13) ◽  
pp. 1910 ◽  
Author(s):  
Zsolt Bor ◽  
Bela Racz
Keyword(s):  

1989 ◽  
Vol 17 (12) ◽  
pp. 862-866
Author(s):  
Katsuo AIZAWA ◽  
Hirobumi KAWABE ◽  
Yukari YASUNAKA ◽  
Yoshihiro TAMACHI
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document