Modeling of the thermodynamics of electrolyte solutions to high temperatures including ion association: application to hydrochloric acid

1990 ◽  
Vol 94 (19) ◽  
pp. 7675-7681 ◽  
Author(s):  
J. M. Simonson ◽  
H. F. Holmes ◽  
R. H. Busey ◽  
R. E. Mesmer ◽  
D. G. Archer ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
High Temperatures ◽  
Ion Association ◽  
Electrolyte Solutions

What can be learnt from dielectric relaxation spectroscopy about ion solvation and association?

2008 ◽  
Vol 80 (6) ◽  
pp. 1239-1252 ◽  
Author(s):  
Richard Buchner
Keyword(s):  
Dielectric Relaxation ◽  
Ion Association ◽  
Electrolyte Solutions ◽  
Ion Solvation ◽  
Dielectric Relaxation Spectroscopy ◽  
Major Focus ◽  
Solvent Interactions ◽  
Solution Studies ◽  
Key Features ◽  
Thermodynamics And Dynamics

Ion solvation and ion association are key features of ion-solvent interactions, and their balance largely determines structure, thermodynamics, and dynamics of electrolyte solutions. Despite being studied for many years with various techniques, these effects are still intriguing because too often results obtained with different methods-each having its individual merits and limitations-cannot be connected properly due to lacking information. In this contribution, we would like to bring dielectric relaxation spectroscopy (DRS) as a further tool for solution studies to the attention of the audience. The principles of DRS and the required instrumentation are briefly introduced. The major focus will be on the kind of results obtained with this technique regarding ion solvation and association and how this information compares with results obtained from other techniques.

Ion association and condensation in primitive models of electrolyte solutions

1999 ◽  
Vol 111 (19) ◽  
pp. 9000-9008 ◽  
Author(s):  
Philip J. Camp ◽  
G. N. Patey
Keyword(s):  
Ion Association ◽  
Electrolyte Solutions

Multiple Ion Association versus Redissociation in Aqueous NaCl and KCl at High Temperatures

2002 ◽  
Vol 106 (28) ◽  
pp. 7121-7134 ◽  
Author(s):  
Andrei V. Sharygin ◽  
Robert H. Wood ◽  
Gregory H. Zimmerman ◽  
Victor N. Balashov
Keyword(s):  
High Temperatures ◽  
Ion Association

scholarly journals An Equation for Computing Thermal Capacity of an Electrolyte in a Dissociated Solution

2019 ◽  
pp. 77-87
Author(s):  
T.E. Akhapkina ◽  
A.A. Gurov ◽  
S.N. Solovev ◽  
S.V. Kozhevnikova
Keyword(s):  
Ion Pairs ◽  
Ion Association ◽  
Electrolyte Solutions ◽  
Thermal Capacity ◽  
Solution Properties ◽  
Association Model

The authors used E.M. Kuznetsova's theory to derive an equation for computing thermal capacity of an electrolyte in a dissociated solution. This equation may also be used to determine such important characteristics as the constant and enthalpy of ion association in electrolyte solutions. This equation is derived from the simplest model, that of ion association, which allows certain solution properties to be adequately described as functions of concentration. The ion association model is based on the equilibrium between ions and ion pairs of the same kind that exists in electrolyte solutions

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