Ion association and the viscosity of dilute electrolyte solutions. Part 1.—Aqueous inorganic salt solutions

1964 ◽  
Vol 60 (0) ◽  
pp. 2075-2084 ◽  
Author(s):  
C. W. Davies ◽  
V. E. Malpass
1989 ◽  
Vol 54 (10) ◽  
pp. 2644-2647 ◽  
Author(s):  
Petr Schneider ◽  
Jiří Rathouský

In porous materials filled with water or water solutions of inorganic salts, water freezes at lower temperatures than under normal conditions; the reason is the decrease of water vapor tension above the convex meniscus of liquid in pores. The freezing point depression is not very significant in pores with radii from 0.05 μm to 10 μm (about 0.01-2.5 K). Only in smaller pores, especially when filled with inorganic salt solutions, this depression is important.


1958 ◽  
Vol 11 (1) ◽  
pp. 1
Author(s):  
R Mills ◽  
EW Godbole

The precision measurement of single ion diffusion coefficients in dilute electrolyte solutions would be of considerable value. A method is described which is capable of giving the required precision. It involves a modification of the open-ended capillary method by enclosure of the capillary of diffusing radioactive material in a scintillator so that its contents can be continually monitored during the course of diffusion.


2008 ◽  
Vol 80 (6) ◽  
pp. 1239-1252 ◽  
Author(s):  
Richard Buchner

Ion solvation and ion association are key features of ion-solvent interactions, and their balance largely determines structure, thermodynamics, and dynamics of electrolyte solutions. Despite being studied for many years with various techniques, these effects are still intriguing because too often results obtained with different methods-each having its individual merits and limitations-cannot be connected properly due to lacking information. In this contribution, we would like to bring dielectric relaxation spectroscopy (DRS) as a further tool for solution studies to the attention of the audience. The principles of DRS and the required instrumentation are briefly introduced. The major focus will be on the kind of results obtained with this technique regarding ion solvation and association and how this information compares with results obtained from other techniques.


2019 ◽  
Vol 35 (2) ◽  
pp. 141-145 ◽  
Author(s):  
Riou KAWAMURA ◽  
Momoka SATOU ◽  
Takuya YONESAKA ◽  
Akio YUCHI

1999 ◽  
Vol 111 (19) ◽  
pp. 9000-9008 ◽  
Author(s):  
Philip J. Camp ◽  
G. N. Patey

1994 ◽  
Vol 28 (1) ◽  
pp. 9-16 ◽  
Author(s):  
Yutaka Sakakihara ◽  
Joseph R.V. Flora ◽  
Makram T. Suidan ◽  
Pratim Biswas ◽  
Masao Kuroda

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