Self-association of acetic acid in some organic solvents

1988 ◽  
Vol 92 (23) ◽  
pp. 6768-6772 ◽  
Author(s):  
Yukio Fujii ◽  
Hiromichi Yamada ◽  
Masateru Mizuta
ChemInform ◽  
1989 ◽  
Vol 20 (10) ◽  
Author(s):  
Y. FUJII ◽  
H. YAMADA ◽  
M. MIZUTA

2016 ◽  
Vol 12 ◽  
pp. 1566-1572 ◽  
Author(s):  
Anne L Schöffler ◽  
Ata Makarem ◽  
Frank Rominger ◽  
Bernd F Straub

A dinuclear N-heterocyclic carbene (NHC) copper complex efficiently catalyzes azide–alkyne cycloaddition (CuAAC) “click” reactions. The ancillary ligand comprises two 4,5-dimethyl-1,3-thiazol-2-ylidene units and an ethylene linker. The three-step preparation of the complex from commercially available starting compounds is more straightforward and cost-efficient than that of the previously described 1,2,4-triazol-5-ylidene derivatives. Kinetic experiments revealed its high catalytic CuAAC activity in organic solvents at room temperature. The activity increases upon addition of acetic acid, particularly for more acidic alkyne substrates. The modular catalyst design renders possible the exchange of N-heterocyclic carbene, linker, sacrificial ligand, and counter ion.


1983 ◽  
Vol 28 (3) ◽  
pp. 328-330 ◽  
Author(s):  
Renzo Carta ◽  
Stella Dernini
Keyword(s):  

2013 ◽  
Vol 48 (14) ◽  
pp. 2164-2169 ◽  
Author(s):  
Travis H. Russell ◽  
Robert M. Counce ◽  
Jack S. Watson ◽  
Barry B. Spencer ◽  
Guillermo D. Del Cul

CrystEngComm ◽  
2015 ◽  
Vol 17 (21) ◽  
pp. 3961-3973 ◽  
Author(s):  
Donal Mealey ◽  
Denise M. Croker ◽  
Åke C. Rasmuson

Nucleation of salicylic acid in different solvents becomes gradually more difficult in the order: chloroform, ethyl acetate, acetonitrile, acetone, methanol and acetic acid. By comparing the results of metastable zone width and induction time experiments new insights are obtained.


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