Thermal decomposition of energetic materials. 18. Relationship of molecular composition to nitrous acid formation: bicyclo and spiro tetranitramines

1986 ◽  
Vol 90 (26) ◽  
pp. 6848-6853 ◽  
Author(s):  
T. B. Brill ◽  
Y. Oyumi
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials ◽  
Nitrous Acid ◽  
Molecular Composition ◽  
Acid Formation ◽  
Relationship Of

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

Thermal decomposition of energetic materials

1991 ◽  
Vol 181 ◽  
pp. 71-77 ◽  
Author(s):  
J.K. Chen ◽  
T.B. Brill
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials

Early Thermal Decay of Energetic Hydrogen- and Nitro-Free Furoxan Compounds: The Case of DNTF and BTF

2021 ◽  
Author(s):  
Shuangfei Zhu ◽  
Wei Yang ◽  
Qiang Gan ◽  
Nianshou Cheng ◽  
Changgen Feng
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials ◽  
Decomposition Mechanism ◽  
Thermal Decomposition Mechanism ◽  
Thermal Decay

Exploring the initial reactions of H-free and nitro-free energetic materials could enrich our understanding into the thermal decomposition mechanism of various energetic materials (EMs). In this work, two furoxan compounds,...

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