Formation of electronically excited nitric oxide and energy partitioning in the 193-nm photolysis of the nitric oxide dimer

1985 ◽  
Vol 89 (13) ◽  
pp. 2725-2727 ◽  
Author(s):  
O. Kajimoto ◽  
K. Honma ◽  
T. Kobayashi
Keyword(s):  
Nitric Oxide ◽  
Energy Partitioning ◽  
Electronically Excited ◽  
Nitric Oxide Dimer ◽  
193 Nm

A theoretical determination of the dissociation energy of the nitric oxide dimer

1994 ◽  
Vol 88 (6) ◽  
pp. 425-435 ◽  
Author(s):  
Remedios Gonz�lez-Luque ◽  
Manuela Merch�n ◽  
Bj�rn O. Roos
Keyword(s):  
Nitric Oxide ◽  
Dissociation Energy ◽  
Theoretical Determination ◽  
Nitric Oxide Dimer

Vibrational predissociation dynamics of the nitric oxide dimer

2018 ◽  
Vol 72 (7) ◽  
Author(s):  
Olivia Borrell-Grueiro ◽  
Ubaldo Baños-Rodríguez ◽  
Maykel Márquez-Mijares ◽  
Jesús Rubayo-Soneira
Keyword(s):  
Nitric Oxide ◽  
Vibrational Predissociation ◽  
Nitric Oxide Dimer

Generation of electronically excited products in the multiphoton dissociation of phosgene at 193 nm

1983 ◽  
Author(s):  
M. W. Wilson ◽  
M. Rothschild ◽  
C. K. Rhodes ◽  
Test ◽  
Carole S. Allman ◽  
...  
Keyword(s):  
Electronically Excited ◽  
Multiphoton Dissociation ◽  
193 Nm

The Nitric Oxide Dimer Reaction in Carbon Nanopores

2017 ◽  
Vol 122 (13) ◽  
pp. 3604-3614 ◽  
Author(s):  
Deepti Srivastava ◽  
C. Heath Turner ◽  
Erik E. Santiso ◽  
Keith E. Gubbins
Keyword(s):  
Nitric Oxide ◽  
Nitric Oxide Dimer

THE Hg 6(3P1)-PHOTOSENSITIZED DECOMPOSITION OF NITRIC OXIDE

1961 ◽  
Vol 39 (12) ◽  
pp. 2549-2555 ◽  
Author(s):  
Otto P. Strausz ◽  
Harry E. Gunning
Keyword(s):  
Nitric Oxide ◽  
Quantum Yield ◽  
Ground State ◽  
Pressure Range ◽  
Oxides Of Nitrogen ◽  
Total Rate ◽  
A Value ◽  
Electronically Excited ◽  
Static Conditions ◽  
Observed Behavior

The reaction of NO with Hg 6(3P1) atoms has been studied under static conditions at 30°, over the pressure range 1–286 mm. The products were found to be N2, N2O, and higher oxides of nitrogen. At NO pressures exceeding 4 mm, the total rate of formation of N2+N2O was constant, while the ratio N2O/N2 increased linearly with the substrate pressure. The rate was found to vary directly with the first power of the intensity at 2537 Å, and a value of 1.9 × 10−3 moles/einstein was established for the quantum yield of N2 + N2O production. In the proposed mechanism, reaction is attributed to the decomposition of an energy-rich dimer, (NO)2*, which is formed by the collision of electronically excited (4II) NO molecules with those in the ground state. The (NO)2* species is assumed to decompose by the steps: (NO)2* → N2 + O2 and (NO)2* + NO → N2O + NO2. The mechanism satisfactorily explains the observed behavior of the system.

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