FTIR spectra of and the hydrogen bonding in matrix-isolated molecular complexes of hydrogen oxides, carbon monoxide, and carbon dioxide formed in the photooxidation of isotopic formaldehydes and glyoxal in solid molecular hydrogen at 12-15 K

1985 ◽  
Vol 89 (9) ◽  
pp. 1618-1631 ◽  
Author(s):  
Tai Ly Tso ◽  
Edward K. C. Lee
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Bonding ◽  
Molecular Hydrogen ◽  
Molecular Complexes ◽  
Ftir Spectra

Second-Sphere Hydrogen-Bonding Enhances Heterogeneous Electrocatalytic CO2 to CO Reduction by Iron Porphyrin in water

2021 ◽  
Author(s):  
Ally Aukauloo ◽  
Chanjuan Zhang ◽  
Diana Dragoe ◽  
François Brisset ◽  
Bernard Boitrel ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bonding ◽  
Selective Reduction ◽  
Molecular Complexes ◽  
Cost Effective ◽  
Iron Porphyrin ◽  
Carbon Dioxide Co2 ◽  
Co Reduction

Intense efforts are currently being injected in discovering cost-effective catalysts for the selective reduction of carbon dioxide (CO2). Much advances have indeed been realized in the design of molecular complexes...

scholarly journals Controlled atmosphere GMAW welding of transportation vehicles and production machines parts made from 30MnB5 steel

2018 ◽  
Vol 216 ◽  
pp. 03001 ◽  
Author(s):  
Evgeny Ivanayskiy ◽  
Aleksei Ishkov ◽  
Aleksandr Ivanayskiy ◽  
Iakov Ochakovskii
Keyword(s):  
Mechanical Properties ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Chemical Composition ◽  
Controlled Atmosphere ◽  
Shielding Gas ◽  
Reducing Atmosphere ◽  
Metal Composition ◽  
Gmaw Welding ◽  
Welding Materials

The paper studies the influence of shielding gas on the composition and the structure of weld joint metal of 30MnB5 steel applied in essential parts of automobiles and tractors. The welding was performed in inert, oxidizing and reducing atmospheres. It was established that TIG welding with argon used as shielding gas did not provide the required mechanical properties when using conventional welding materials. Carbon dioxide during MAG welding caused partial burning of alloying elements. Carbon monoxide used as shielding gas was proved to form reducing atmosphere enabling to obtain chemical composition close to the base metal composition. Metallographic examinations were carried out. The obtained results provided full-strength weld, as well as the required reliability and durability of welded components and joints.

Low-Carbon Monoxide Hydrogen by Sorption-Enhanced Reaction

2003 ◽  
Vol 1 (1) ◽  
Author(s):  
Douglas P Harrison ◽  
Zhiyong Peng
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Production ◽  
Proton Exchange Membrane ◽  
Primary Energy ◽  
Proton Exchange ◽  
Raw Material ◽  
Impurity Level ◽  
Low Carbon ◽  
Enhanced Production

Hydrogen is an increasingly important chemical raw material and a probable future primary energy carrier. In many current and anticipated applications the carbon monoxide impurity level must be reduced to low-ppmv levels to avoid poisoning catalysts in downstream processes. Methanation is currently used to remove carbon monoxide in petroleum refining operations while preferential oxidation (PROX) is being developed for carbon monoxide control in fuel cells. Both approaches add an additional step to the multi-step hydrogen production process, and both inevitably result in hydrogen loss. The sorption enhanced process for hydrogen production, in which steam-methane reforming, water-gas shift, and carbon dioxide removal reactions occur simultaneously in the presence of a nickel-based reforming catalyst and a calcium-based carbon dioxide sorbent, is capable of producing high purity hydrogen containing minimal carbon monoxide in a single processing step. The process also has the potential for producing pure CO2 that is suitable for subsequent use or sequestration during the sorbent regeneration step. The current research on sorption-enhanced production of low-carbon monoxide hydrogen is an extension of previous research in this laboratory that proved the feasibility of producing 95+% hydrogen (dry basis), but without concern for the carbon monoxide concentration. This paper describes sorption-enhanced reaction conditions – temperature, feed gas composition, and volumetric feed rate – required to produce 95+% hydrogen containing low carbon monoxide concentrations suitable for direct use in, for example, a proton exchange membrane fuel cell.

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