Laser-induced temperature jump measurements in the kinetics of association and dissociation of the nitrogen oxide (N2O3) + M = nitrogen dioxide + nitrous oxide + M system

1993 ◽  
Vol 97 (20) ◽  
pp. 5260-5265 ◽  
Author(s):  
B. Markwalder ◽  
P. Gozel ◽  
H. van den Bergh
Keyword(s):  
Nitrous Oxide ◽  
Nitrogen Dioxide ◽  
Nitrogen Oxide ◽  
Temperature Jump ◽  
Kinetics Of

Kinetics of catalytic reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Rate Equation ◽  
Catalytic Reduction ◽  
Zero Order ◽  
Spectroscopic Measurements ◽  
First Order ◽  
Ir Spectroscopic ◽  
Kinetics Of ◽  
Al2o3 Catalyst

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.

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