scholarly journals Comparison of the kinetics of ribo-, deoxyribo- and hybrid oligonucleotide double-strand formation by temperature-jump kinetics

Biochemistry ◽  
1982 ◽  
Vol 21 (21) ◽  
pp. 5289-5295 ◽  
Author(s):  
Jeffrey W. Nelson ◽  
Ignacio Tinoco
Keyword(s):  
Temperature Jump ◽  
Kinetics Of

Laser Temperature Jump Study of the Helix⇌Coil Kinetics of an Alanine Peptide Interpreted with a ‘Kinetic Zipper' Model

Biochemistry ◽  
1997 ◽  
Vol 36 (30) ◽  
pp. 9200-9210 ◽  
Author(s):  
Peggy A. Thompson ◽  
William A. Eaton ◽  
James Hofrichter
Keyword(s):  
Temperature Jump ◽  
Laser Temperature Jump ◽  
Kinetics Of

The Kinetic Activation Volumes for the Binding of Iodide to Cobalamin (Vitamin B12) Studied on a High Pressure Laser Temperature Jump Apparatus

1974 ◽  
Vol 52 (6) ◽  
pp. 910-914 ◽  
Author(s):  
Brian B. Hasinoff
Keyword(s):  
High Pressure ◽  
Metal Ion ◽  
Temperature Jump ◽  
Outer Sphere ◽  
Dissociation Rate ◽  
Vitamin B ◽  
Laser Temperature Jump ◽  
Dissociation Rate Constants ◽  
Kinetics Of ◽  
Activated Complex

The relaxation kinetics of the reaction of iodide with cobalamin (vitamin B12) were studied on a high pressure laser temperature jump apparatus in aqueous solution at 25° and ionic strength 0.2 M. Analysis of the pressure dependence of the formation and dissociation rate constants gave their respective volumes of activation to be: ΔVf* = 5.50 ± 0.8 cm3 mol−1 and ΔVd* = 11.5 ± 1.6 cm3 mol−1 The positive activation volume for formation of the complex, ΔVf*, after appropriate correction for the volume change due to formation of an outer sphere complex, is consistent with a dissociative type mechanism in which the metal ion – water bond is stretched in the activated complex.

Temperature-Jump Investigations of the Kinetics of Hydrogel Nanoparticle Volume Phase Transitions

2001 ◽  
Vol 123 (45) ◽  
pp. 11284-11289 ◽  
Author(s):  
Jianping Wang ◽  
Daoji Gan ◽  
L. Andrew Lyon ◽  
Mostafa A. El-Sayed
Keyword(s):  
Phase Transitions ◽  
Temperature Jump ◽  
Volume Phase ◽  
Kinetics Of
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